Zeki, KetrinYabas, EbruErden, FuatSalih, BekirCanlica, Mevlude2024-10-262024-10-2620240277-53871873-3719https://doi.org/10.1016/j.poly.2024.117138https://hdl.handle.net/20.500.12418/30324This paper focuses on the preparation of 3,5-di-tert-butylphenoxy substituted Lu, Sm, and Y-based double-decker phthalocyanines (Pcs), and investigation of their PDT properties. Briefly, 1,8,15,22-tetra-(3,5-di-tert-butylphenoxy) bisphthalocyanine derivatives (denoted LuPc2-3, SmPc2-4, YPc2-5) were synthesized by a two-step process. First, metal-free 1,8,15,22-tetra-(3,5-di-tert-butylphenoxy)phthalocyanine was prepared by tetramerization of 3,5-di-tert-butylphenoxy phthalonitrile, which is followed by reaction of different lanthanide salts with 1,8,15,22-tetra-(3,5-di-tert-butylphenoxy)bisphthalocyanine. The resultant double-decker Pcs were characterized in detail by UV-Vis, FT-IR, 1H NMR, fluorescence spectroscopy, MALDI-TOF MS, and elemental analysis. Strikingly, we report that double-decker phthalocyanines are not only photostable, but also exhibit relatively high singlet oxygen quantum yields of 0.96 (LuPc2-3), 0.91 (SmPc2-4) 0.87 (YPc2-5) and in THF.en10.1016/j.poly.2024.117138info:eu-repo/semantics/closedAccessPhotodynamic therapyPhotosensitizerSinglet oxygenDouble-decker phthalocyaninesRare earth metalsArticle2612-s2.0-85198994497Q2WOS:001276471700001N/A