Adsorptive features of chitosan entrapped in polyacrylamide hydrogel for Pb2+, UO22+, and Th4+

Abstract

Chitosan (Ch) was entrapped in polyacrylamide (PAA) by direct polymerization of acrylamide in a suspension of Ch. The adsorptive features of PAA-Ch and Ch were then investigated for pb(2+), UO22+, and Th4+ in view of dependency on ion concentration, temperature, and kinetics. Additional considerations were also given to their ion selectivity and reusability. Isotherms were L and H type of Giles classification and evaluated with reference to Langmuir, Freundlich, and Dubinin-Radushkevich (DR) models. PAA-Ch had higher adsorption capacity than Ch for all studied ions so that the sequences were Th4+ > Pb2+ > UO22+ concordantly with their affective ionic charges. The affinity of Ch in PAA increased for Pb2+ and UO22+ but did not change for Th4+. The values of enthalpy and entropy changed were positive for all studied ions for both Ch and PAA-Ch. The negative free enthalpy change value indicated that the adsorption process is spontaneous in the sequence of Th4+ >= Pb2+ > UO22+. Free energy values derived from DR model implied that the sorption process is the ion exchange. Well compatibility of adsorption kinetics to the pseudosecond-order model predicate that the rate-controlling step is a chemical sorption. The study for ion selectivity showed that both Ch and PAA-Ch had the highest affinity to Pb2+. The reusability tests for Ch and PAA-Ch for Pb2+ for five uses showed that complete recovery of the ion was possible. The studied features of PAA-Ch suggest that the material should be considered as a new adsorbent. It is envisaged that the use of Ch in PAA will enhance practicality and effectiveness of Ch in separation and removal procedures. (C) 2007 Elsevier B.V. All rights reserved.