Effective removal of Allura red food dye from water using cross-linked chitosan-diatomite composite beads

Abstract

Chitosan (Ch)-diatomite (D) composite beads (Ch-D) were synthesized using epichlorohydrin and tripolyphosphate crosslinkers and then moulded into uniform beads in tripolyphosphate solution. FT-IR and SEM-EDX analyses showed that Ch-D composite adsorbent was successfully synthesized by functionalization of chitosan to Ch-D by hydrogen bonding and electrostatic interactions and improved adsorption capacity for removal of Allura red AC (AR) food dye. The removal rate of AR food dye was found to be 98 % at 25 ◦C, natural AR dye pH value, 24 h, and at the initial AR dye concentration of 200 mg L− 1. The maximum adsorption capacity was found to be 34.7 mg g− 1. It was observed that π-π interactions, hydrogen bonds, and electrostatic interactions between the functional groups containing oxygen and amine on the surface of the Ch-D composite and the functional groups of the anionic AR dye, and AR dye adsorption via complexation took place. In light of all this information, the Ch-D composite adsorbent is a promising potential material for the effective treatment of colored pollutants from wastewater.