dc.contributor.author | Çelik, Muhammed Safa; Çetinus, Şenay Akkuş; Yenidünya, Ali Fazıl, Çetinkaya, Serap; Tüzün, Burak | |
dc.date.accessioned | 2024-03-06T09:34:45Z | |
dc.date.available | 2024-03-06T09:34:45Z | |
dc.date.issued | 2023 | tr |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/14738 | |
dc.description.abstract | Water-soluble basic rhodamine B (RhB) was adsorbed onto fruit powders of Rhus coriaria L. (Anacar-diaceae), sumac in batch reactions. Adsorption was optimized by employing concentration, pH, and time parameters. Experimental data were in accordance with the Freundlich isotherm, adsorption obeyed the pseudo-second-order kinetics, and thermodynamic parameters indicated that adsorption was exothermic, spontaneous, and chemical. Results were also evaluated by theoretical means: lowest Unoccupied Molec-ular Orbitals (LUMO), and the Highest Occupied Molecular Orbitals (HOMO). The HOMO energy values of the rhodamine B molecule had the highest activity with-3.3729 at the B3LYP level,-6.0361 at the HF level, and-4.3299 at the M062X level. In the calculations made, it was seen that the rhodamine B molecule has more electron density on the oxygen molecules. Taken together, the findings suggested that the dried fruit of the Rhus coriaria L. could be a useful biosorbent for the removal of dyes from aqueous media. (c) 2022 Elsevier B.V. All rights reserved. | tr |
dc.language.iso | eng | tr |
dc.publisher | Elsevier | tr |
dc.relation.isversionof | DOI10.1016/j.molstruc.2022.134158 | tr |
dc.rights | info:eu-repo/semantics/openAccess | tr |
dc.subject | Biosorption, DFT, Rhodamine B, Rhus coriaria L. ( Anacardiaceae ) | tr |
dc.title | Biosorption of Rhodamine B dye from aqueous solution by Rhus coriaria L. plant: Equilibrium, kinetic, thermodynamic and DFT calculations | tr |
dc.type | article | tr |
dc.relation.journal | JOURNAL OF MOLECULAR STRUCTURE | tr |
dc.contributor.department | Fen Fakültesi | tr |
dc.contributor.authorID | https://orcid.org/0000-0001-5705-6839 | tr |
dc.identifier.volume | 1272 | tr |
dc.identifier.issue | 134158 | tr |
dc.identifier.endpage | 10 | tr |
dc.identifier.startpage | 1 | tr |
dc.relation.publicationcategory | Ulusal Hakemli Dergide Makale - Kurum Öğretim Elemanı | tr |