| dc.description.abstract | In this article, direct N-alkylation reactions of amines with alcohols derivatives have been investigated. For this purpose, a new series ruthenium (II) complexes bearing N-coordinated benzimidazole complexes with have been synthesized and fully characterized by elemental analysis, FT-IR, 1H NMR and, 13C NMR spectroscopies. Additionally, the structures of the complexes 2b and 2c have been confirmed by X-ray crystallography. Although the N-alkylating reaction is usually performed in toluene, the catalytic study of complexes 2a-d has carried out no additional solvent and alcohol acted both as solvent and reactant of alkylating by using a little excess of alcohols. Surprisingly, conversion and selectivity of amine product for alkylation reaction have been seen high in medium solvent-free relative to in toluene. © 2018 John Wiley & Sons, Ltd. | en_US |
| dc.contributor.department | Şahin, N., Department of Basic Education, University of Cumhuriyet Faculty of Education, Sivas, 58140, Turkey, Department of Chemistry, University, University of İnönü Faculty of Science and Art, Malatya, 44280, Turkey, University of İnönü Catalysis Research and Application Center, Malatya, 44280, Turkey -- Özdemir, N., Faculty of Education, University of Ondokuz Mayıs Department of Mathematics and Science Education, Samsun, 55139, Turkey -- Gürbüz, N., Department of Chemistry, University, University of İnönü Faculty of Science and Art, Malatya, 44280, Turkey, University of İnönü Catalysis Research and Application Center, Malatya, 44280, Turkey -- Özdemir, İ., Department of Chemistry, University, University of İnönü Faculty of Science and Art, Malatya, 44280, Turkey, University of İnönü Catalysis Research and Application Center, Malatya, 44280, Turkey | en_US |
