| dc.contributor.author | Altan, Orhan | |
| dc.contributor.author | Serindag, Osman | |
| dc.contributor.author | Sayin, Koray | |
| dc.contributor.author | Karakas, Duran | |
| dc.date.accessioned | 2019-07-27T12:10:23Z | |
| dc.date.accessioned | 2019-07-28T09:47:09Z | |
| dc.date.available | 2019-07-27T12:10:23Z | |
| dc.date.available | 2019-07-28T09:47:09Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1042-6507 | |
| dc.identifier.issn | 1563-5325 | |
| dc.identifier.uri | https://dx.doi.org/10.1080/10426507.2015.1119827 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12418/7632 | |
| dc.description | WOS: 000380942400007 | en_US |
| dc.description.abstract | Novel phosphine oxides, (((3-methylpyridin-2-yl)amino)methyl)diphenylphosphine oxide (1) and diphenyl((pyrazin-2-ylamino)methyl)phosphine oxide (2), were synthesized and characterized. Phosphines ligands (3 and 4) were obtained by the reduction of 1 and 2 with AlH3, monitored by P-31 NMR spectroscopy. Pd(II) complexes of 3 and 4 were synthesized and characterized (5 and 6). The catalytic activity of 5 and 6 was tested on the reaction of styrene with both activated and deactivated aryl bromides in air. The results of the catalytic experiments were discussed through DFT calculations. [GRAPHICS] | en_US |
| dc.description.sponsorship | Cukurova University Scientific Research Projects [FEF2009D7] | en_US |
| dc.description.sponsorship | This work was supported by Cukurova University Scientific Research Projects (FEF2009D7). | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | TAYLOR & FRANCIS LTD | en_US |
| dc.relation.isversionof | 10.1080/10426507.2015.1119827 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Phosphine ligands | en_US |
| dc.subject | palladium complexes | en_US |
| dc.subject | Heck reaction | en_US |
| dc.subject | DFT calculations | en_US |
| dc.title | Pd(II) complexes of novel phosphine ligands: Synthesis, characterization, and catalytic activities on Heck reaction | en_US |
| dc.type | article | en_US |
| dc.relation.journal | PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | en_US |
| dc.contributor.department | [Altan, Orhan] Mersin Univ, Tech Sci Vocat Sch, Dept Chem, TR-33343 Mersin, Turkey -- [Serindag, Osman] Kanuni Univ, Inst Sci, Adana, Turkey -- [Sayin, Koray -- Karakas, Duran] Cumhuriyet Univ, Dept Chem, Fac Sci, Sivas, Turkey | en_US |
| dc.contributor.authorID | ALTAN, Orhan -- 0000-0003-3510-0733 | en_US |
| dc.identifier.volume | 191 | en_US |
| dc.identifier.issue | 7 | en_US |
| dc.identifier.endpage | 999 | en_US |
| dc.identifier.startpage | 993 | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
