dc.contributor.author | Ulusoy, Halil Ibrahim | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:56:33Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:56:33Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1759-9660 | |
dc.identifier.issn | 1759-9679 | |
dc.identifier.uri | https://dx.doi.org/10.1039/c4ay02691h | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/8053 | |
dc.description | WOS: 000349679300018 | en_US |
dc.description.abstract | A preconcentration and determination methodology utilizing the cloud point phenomenon was developed for the determination of inorganic selenium species using UV-VIS spectrophotometry. The cloud point extraction method was based on the selective formation of a complex between selenium(IV) ions and 4,5-diamino-6-hydroxy-2-mercapto pyrimidine (DAHMP). Then, the formed stable complex was extracted to a nonionic surfactant phase of Triton X-114. After phase separation was carried out via decantation, the surfactant-rich phase was diluted with 20% ethanol solution and the absorbance signal was measured at 458 nm using an UV-VIS spectrophotometer. Under the optimized conditions, linear calibration curves were obtained over a range of 20-1500 ng mL(-1) with detection and quantification limits of 6.06 ng mL(-1) and 19.89 ng mL(-1), respectively. The relative standard deviation was 2.80% for 5 replicate measurements at 250 mu g L-1 concentration level. The proposed method is very versatile and economic as only a conventional spectrophotometer is used for the measurements. The method was validated by the analysis of two certified reference materials and a recovery test. Finally, the method was applied to the determination of the total Se amount in real samples including water samples and hen eggs containing selenium. | en_US |
dc.description.sponsorship | Cumhuriyet University Scientic Research Projects Commission [ECZ-002] | en_US |
dc.description.sponsorship | This study has been supported by the Cumhuriyet University Scientic Research Projects Commission as the research project with the ECZ-002 code. The author gratefully thanks Prof. Dr Ramazan GURKAN and Asst. Prof. Dr Tulay OYMAK for their useful comments and contributions to the preparation of the project text. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | ROYAL SOC CHEMISTRY | en_US |
dc.relation.isversionof | 10.1039/c4ay02691h | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Simple and useful method for determination of inorganic selenium species in real samples based on UV-VIS spectroscopy in a micellar medium | en_US |
dc.type | article | en_US |
dc.relation.journal | ANALYTICAL METHODS | en_US |
dc.contributor.department | Cumhuriyet Univ, Dept Analyt Chem, Fac Pharm, TR-58140 Sivas, Turkey | en_US |
dc.contributor.authorID | Ulusoy, Halil Ibrahim -- 0000-0002-8742-5145 | en_US |
dc.identifier.volume | 7 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.endpage | 960 | en_US |
dc.identifier.startpage | 953 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |