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dc.contributor.authorMCNEILL, IC
dc.contributor.authorGORMAN, JG
dc.contributor.authorBASAN, S
dc.date.accessioned2019-07-27T12:10:23Z
dc.date.accessioned2019-07-28T10:38:57Z
dc.date.available2019-07-27T12:10:23Z
dc.date.available2019-07-28T10:38:57Z
dc.date.issued1991
dc.identifier.issn0141-3910
dc.identifier.urihttps://dx.doi.org/10.1016/0141-3910(91)90020-R
dc.identifier.urihttps://hdl.handle.net/20.500.12418/11989
dc.descriptionWOS: A1991FX77800008en_US
dc.description.abstractThe thermal degradation of PVC-PTMS blends has been studied over the whole composition range, using thermal volatilisation analysis and thermogravimetry. In the TVA studies, degradation products have been separated and investigated and in the TG experiments both temperature programmed and isothermal conditions have been used. It has been found that these blends are homogeneous over most of the composition range when cast as films from solution. Powder mixtures of the two polymers show no evidence of interaction during degradation, but in the case of film blends, the PVC is stabilised at low to moderate PTMS contents and destabilised at very high PTMS concentrations. There is an increase in the residue of degradation to 500-degrees-C in most of the blends. The interactions are explained in terms of reaction of chlorine chain carriers in the PVC dehydrochlorination with methylene groups in the PTMS, followed by crosslinking of macroradicals.en_US
dc.language.isoengen_US
dc.publisherELSEVIER SCI LTDen_US
dc.relation.isversionof10.1016/0141-3910(91)90020-Ren_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleTHERMAL-DEGRADATION OF BLENDS OF PVC WITH POLY(TETRAMETHYLENE SEBACATE)en_US
dc.typearticleen_US
dc.relation.journalPOLYMER DEGRADATION AND STABILITYen_US
dc.contributor.departmentCUMHURIYET UNIV,DEPT CHEM,SIVAS 58140,TURKEYen_US
dc.identifier.volume33en_US
dc.identifier.issue2en_US
dc.identifier.endpage276en_US
dc.identifier.startpage263en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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