dc.contributor.author | Celik, Muhammed Safa | |
dc.contributor.author | Cetinus, Senay Akkus | |
dc.contributor.author | Yenidunya, Ali Fazıl | |
dc.contributor.author | Cetinkaya, Serap | |
dc.contributor.author | Tüzün,Burak | |
dc.date.accessioned | 2024-01-09T12:16:30Z | |
dc.date.available | 2024-01-09T12:16:30Z | |
dc.date.issued | 16 September 2022 | tr |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/14221 | |
dc.description.abstract | Water-soluble basic rhodamine B (RhB) was adsorbed onto fruit powders of Rhus coriaria L. (Anacar- diaceae), sumac in batch reactions. Adsorption was optimized by employing concentration, pH, and time parameters. Experimental data were in accordance with the Freundlich isotherm, adsorption obeyed the pseudo-second-order kinetics, and thermodynamic parameters indicated that adsorption was exothermic, spontaneous, and chemical. Results were also evaluated by theoretical means: lowest Unoccupied Molec- ular Orbitals (LUMO), and the Highest Occupied Molecular Orbitals (HOMO). The HOMO energy values of the rhodamine B molecule had the highest activity with -3.3729 at the B3LYP level, -6.0361 at the HF level, and -4.3299 at the M062X level. In the calculations made, it was seen that the rhodamine B molecule has more electron density on the oxygen molecules. Taken together, the findings suggested that the dried fruit of the Rhus coriaria L. could be a useful biosorbent for the removal of dyes from aqueous media. | tr |
dc.language.iso | eng | tr |
dc.publisher | Journal of Molecular Structure | tr |
dc.relation.isversionof | https://doi.org/10.1016/j.molstruc.2022.134158 | tr |
dc.rights | info:eu-repo/semantics/openAccess | tr |
dc.subject | Biosorption | tr |
dc.subject | DFT | tr |
dc.subject | Rhodamine B | tr |
dc.subject | Rhus coriaria L. ( Anacardiaceae ) | tr |
dc.title | Biosorption of Rhodamine B dye from aqueous solution by Rhus coriaria L. plant: Equilibrium, kinetic, thermodynamic and DFT calculations | tr |
dc.type | article | tr |
dc.contributor.department | Sivas Meslek Yüksekokulu | tr |
dc.contributor.authorID | https://orcid.org/0000-0002-0420-2043 | tr |
dc.identifier.volume | 1272 | tr |
dc.identifier.startpage | 134158 | tr |
dc.relation.publicationcategory | Uluslararası Editör Denetimli Dergide Makale | tr |