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dc.contributor.authorHalil İbrahim Ulusoy
dc.contributor.authorRamazan Gürkan
dc.contributor.authorMehmet Akçay
dc.date.accessioned23.07.201910:49:13
dc.date.accessioned2019-07-23T16:26:55Z
dc.date.available23.07.201910:49:13
dc.date.available2019-07-23T16:26:55Z
dc.date.issued2011
dc.identifier.issn1300-0527
dc.identifier.urihttp://www.trdizin.gov.tr/publication/paper/detail/TVRFM05ETXpNdz09
dc.identifier.urihttps://hdl.handle.net/20.500.12418/1914
dc.description.abstractIn the present study, a novel catalytic-kinetic spectrophotometric method was developed for the determination of trace amounts of copper. It is based on the catalytic effect of Cu(II) on the reduction of brilliant cresyl blue (BCB) by ascorbic acid in pH 5.0 acetate buffer medium. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of BCB at 624 nm. The operating conditions regarding concentration of reagents, pH, time, and temperature were established and optimized in detail. The working curve was linear in the concentration range of 0.1-5.0 μg L −1 . The maximum percentage error and standard deviation for 5 replicate determination of the 3 μg L −1 Cu(II) were 3.20 and 0.45, respectively. The detection limit and quantification limit were 0.025 and 0.086 μg L −1 , respectively. The procedure was successfully applied to determination of dissolved copper levels of 3 different natural spring waters and artificially prepared wastewater samples. The accuracy of the proposed kinetic method was tested by means of 5 replicate analyses of the certified standard materials, SRM 1640, based on 2 independent methods.en_US
dc.description.abstractIn the present study, a novel catalytic-kinetic spectrophotometric method was developed for the determination of trace amounts of copper. It is based on the catalytic effect of Cu(II) on the reduction of brilliant cresyl blue (BCB) by ascorbic acid in pH 5.0 acetate buffer medium. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of BCB at 624 nm. The operating conditions regarding concentration of reagents, pH, time, and temperature were established and optimized in detail. The working curve was linear in the concentration range of 0.1-5.0 μg L −1 . The maximum percentage error and standard deviation for 5 replicate determination of the 3 μg L −1 Cu(II) were 3.20 and 0.45, respectively. The detection limit and quantification limit were 0.025 and 0.086 μg L −1 , respectively. The procedure was successfully applied to determination of dissolved copper levels of 3 different natural spring waters and artificially prepared wastewater samples. The accuracy of the proposed kinetic method was tested by means of 5 replicate analyses of the certified standard materials, SRM 1640, based on 2 independent methods.en_US
dc.language.isoengen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMühendisliken_US
dc.subjectKimyaen_US
dc.titleKinetic spectrophotometric determination of trace copper(II) ions by their catalytic effect on the reduction of brilliant cresyl blue by ascorbic aciden_US
dc.typearticleen_US
dc.relation.journalTurkish Journal of Chemistryen_US
dc.contributor.departmentSivas Cumhuriyet Üniversitesien_US
dc.identifier.volume35en_US
dc.identifier.issue4en_US
dc.identifier.endpage612en_US
dc.identifier.startpage599en_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US]


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