dc.contributor.author | Ulusoy, Halil Ibrahim | |
dc.contributor.author | Yilmaz, Erkan | |
dc.contributor.author | Soylak, Mustafa | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:37:11Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:37:11Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 0026-265X | |
dc.identifier.issn | 1095-9149 | |
dc.identifier.uri | https://dx.doi.org/10.1016/j.microc.2018.11.056 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/5964 | |
dc.description | WOS: 000457513000108 | en_US |
dc.description.abstract | A new hybrid material was synthesized including magnetic graphene oxide/multiwalled carbon nanotube core shell (GO/MWCNT/Fe3O4/SiO2) and used as magnetic solid phase extraction adsorbent for separation and pre concentration of paracetamol and caffeine subsequent detection by high performance liquid chromatography. The morphology, composition, and properties of the synthesized hybrid material was characterized by Fourier transform infrared spectrometry, Raman spectrometry, X-ray diffraction spectrometry, scanning electron microscopy, mapping photographs and BET surface area analysis. The experimental variables on the extraction efficiency were studied and optimized. The optimum conditions for quantitative extraction of paracetamol and caffeine were obtained as of adsorbent amount, 70 mg; pH, 8.0; and elution with 1 mL of methanol by vortex mixer for 60s. Validation experiments showed that the developed method had good linear ranges 5-800 ng mL(-1) for caffeine and 10-1000 ng mL(-1) for paracetamol, respectively. The limits of detection were found as 1.48 and 3.32 ng mL(-1) for caffeine and paracetamol, respectively. The accuracy of the developed magnetic solid phase extraction method was proved by addition-recovery tests by using model solutions and the developed method was successfully applied for the determination of paracetamol and caffeine in synthetically prepared urine and waste water samples. | en_US |
dc.description.sponsorship | Cumhuriyet University Scientific Research Projects Commission [ECZ-021] | en_US |
dc.description.sponsorship | This study has been supported by Cumhuriyet University Scientific Research Projects Commission as the research project with the ECZ-021 code. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | ELSEVIER SCIENCE BV | en_US |
dc.relation.isversionof | 10.1016/j.microc.2018.11.056 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Hybrid magnetic material | en_US |
dc.subject | Magnetic solid phase extraction | en_US |
dc.subject | High performance liquid chromatography | en_US |
dc.subject | Paracetamol | en_US |
dc.subject | Caffeine | en_US |
dc.title | Magnetic solid phase extraction of trace paracetamol and caffeine in synthetic urine and wastewater samples by a using core shell hybrid material consisting of graphene oxide/multiwalled carbon nanotube/Fe3O4/SiO2 | en_US |
dc.type | article | en_US |
dc.relation.journal | MICROCHEMICAL JOURNAL | en_US |
dc.contributor.department | [Ulusoy, Halil Ibrahim] Cumhuriyet Univ, Fac Pharm, Dept Analyt Chem, TR-58140 Sivas, Turkey -- [Yilmaz, Erkan] Erciyes Univ, Fac Pharm, Dept Analyt Chem, TR-38039 Kayseri, Turkey -- [Soylak, Mustafa] Erciyes Univ, Fac Sci, Dept Chem, TR-38039 Kayseri, Turkey | en_US |
dc.contributor.authorID | Soylak, Mustafa -- 0000-0002-1017-0244; YILMAZ, ERKAN -- 0000-0001-8962-3199 | en_US |
dc.identifier.volume | 145 | en_US |
dc.identifier.endpage | 851 | en_US |
dc.identifier.startpage | 843 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |