dc.contributor.author | Sahin, Neslihan | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:37:12Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:37:12Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.issn | 1872-8014 | |
dc.identifier.uri | https://dx.doi.org/10.1016/j.molstruc.2018.09.064 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/5971 | |
dc.description | WOS: 000450377600023 | en_US |
dc.description.abstract | N-Heterocyclic carbenes (NHCs) have been known to be efficient ligands for the Suzuki-Miyaura cross-coupling. In this work, four novel 2-methyl-2-propenyl substituted N-heterocyclic carbene ligands (1a-d) were synthesized and they were used to produce four novel air-stable PEPPSI-type palladium-NHC complexes (2a-d). All of the new compounds were fully characterized by elemental analysis, H-1, C-13 NMR and FT-IR spectroscopies. In addition, prepared complexes (2a-d) were investigated as catalysts in the Suzuki-Miyaura coupling reaction under very mild conditions using a mixture of i-PrOH/water as a solvent and a base at the room temperature. Under optimal reaction conditions, the expected biaryl products were obtained in moderate to high yields. (C) 2018 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technological Research of Turkey (TUBITAK-BIDEB), the National Research Fellow-ship Programme | en_US |
dc.description.sponsorship | The authors thank the Scientific and Technological Research of Turkey (TUBITAK-BIDEB), the National Research Fellow-ship Programme for grants to N. S. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | ELSEVIER SCIENCE BV | en_US |
dc.relation.isversionof | 10.1016/j.molstruc.2018.09.064 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | N-Heterocyclic carben | en_US |
dc.subject | 2-Methyl-2-propenyl | en_US |
dc.subject | Suzuki-miyaura reaction | en_US |
dc.subject | PEPPSI | en_US |
dc.title | PEPPSI-type 2-methyl-2-propenyl-functionalized N-heterocyclic carbene-palladium complexes: Synthesis, structural characterization and catalytic activity on Suzuki-Miyaura reaction | en_US |
dc.type | article | en_US |
dc.relation.journal | JOURNAL OF MOLECULAR STRUCTURE | en_US |
dc.contributor.department | [Sahin, Neslihan] Cumhuriyet Univ, Fac Educ, Dept Basic Educ, TR-58140 Sivas, Turkey | en_US |
dc.identifier.volume | 1177 | en_US |
dc.identifier.endpage | 198 | en_US |
dc.identifier.startpage | 193 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |