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Synthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical properties

dc.contributor.authorGuzel, Emre
dc.contributor.authorGunsel, Armagan
dc.contributor.authorTuzun, Burak
dc.contributor.authorAtmaca, Goknur Yasa
dc.contributor.authorBilgicli, Ahmet T.
dc.contributor.authorErdogmus, Ali
dc.contributor.authorYarasir, M. Nilufer
dc.date.accessioned2019-07-27T12:10:23Z
dc.date.accessioned2019-07-28T09:37:14Z
dc.date.available2019-07-27T12:10:23Z
dc.date.available2019-07-28T09:37:14Z
dc.date.issued2019
dc.identifier.issn0277-5387
dc.identifier.urihttps://dx.doi.org/10.1016/j.poly.2018.10.072
dc.identifier.urihttps://hdl.handle.net/20.500.12418/5991
dc.descriptionWOS: 000458228500038en_US
dc.description.abstractThis work presents the synthesis of peripherally and non-peripherally tetra-substituted metallophthalocyanines (6-14) containing the 2-(3,4-dimethoxyphenyl)ethanol group. The synthesized compounds were characterized by standard spectroscopy methods. The ligands of the metallophthalocyanines were investigated by quantum chemical calculations. The quantum chemical parameters of these ligands (1 and 2) such as the HOMO, LUMO and chemical hardness were calculated by the B3lyp, HF and M062x methods. The Delta G value of the metal complexes of the ligands were calculated with the obtained results. In addition, photophysical (fluorescence quantum yields) and photochemical (singlet oxygen generation and photodegradation under light irradiation) properties of newly synthesized phthalocyanines were investigated in DMSO solutions, comparatively. (C) 2018 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipSakarya University [BAP-2017-02-04-013]en_US
dc.description.sponsorshipWe thank The Research Fund of Sakarya University (Project no: BAP-2017-02-04-013). This research was made possible by TUBITAK ULAKBIM, High Performance and Grid Computing Center (TR-Grid e-Infrastructure).en_US
dc.language.isoengen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.isversionof10.1016/j.poly.2018.10.072en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectSynthesisen_US
dc.subjectComputational studiesen_US
dc.subjectPhotosensitizeren_US
dc.subjectPhotochemistryen_US
dc.titleSynthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical propertiesen_US
dc.typearticleen_US
dc.relation.journalPOLYHEDRONen_US
dc.contributor.department[Guzel, Emre -- Gunsel, Armagan -- Bilgicli, Ahmet T. -- Yarasir, M. Nilufer] Sakarya Univ, Dept Chem, TR-54050 Serdivan, Sakarya, Turkey -- [Tuzun, Burak] Cumhuriyet Univ, Dept Chem, TR-58140 Sivas, Turkey -- [Atmaca, Goknur Yasa -- Erdogmus, Ali] Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkeyen_US
dc.contributor.authorIDBILGICLI, Ahmet Turgut -- 0000-0002-4144-7357; Guzel, Emre -- 0000-0002-1142-3936; Yarasir, Meryem Nilufer -- 0000-0002-7327-7137; GUNSEL, ARMAGAN -- 0000-0003-1965-1017en_US
dc.identifier.volume158en_US
dc.identifier.endpage324en_US
dc.identifier.startpage316en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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