dc.contributor.author | Karadag, Ahmet | |
dc.contributor.author | Akbas, Huseyin | |
dc.contributor.author | Karakas, Duran | |
dc.contributor.author | Tekin, Kadir Cihan | |
dc.contributor.author | Korkmazer, Erdem | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:37:16Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:37:16Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1300-0527 | |
dc.identifier.uri | https://dx.doi.org/10.3906/kim-1809-56 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/6000 | |
dc.description | WOS: 000473228400004 | en_US |
dc.description.abstract | Protic ionic liquids (PILs) were synthesized through a stoichiometric neutralization reaction between 2,2'-(ethylenedioxy)-bis(ethylamine) {Edbea} and various acids (formic, acetic, boric, decanoic, and gentisic acid). The PILs were characterized by elemental analyses, FTIR, H-1 and C-13 NMR spectroscopy, and thermogravimetric analysis. All the PILs except PIL3 were liquid at room temperature. The viscosity of the PILs (PIL1, 2, 4, 5) was measured using a cone-and-plate viscometer at ambient temperature. Quantum chemical calculations were used to explain the cation/anion ratio in the PILs. Reaction energies in the gas phase calculated at M062X/6-311+G(d,p) level were used to determine the cation/anion ratio. A sliding wear test was conducted at room temperature using an AA7075 disc specimen against a stationary 100Cr6 steel ball. The wear protection of PILs and 15W40 engine oil was determined by considering the volume loss of AA7075. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | SCIENTIFIC TECHNICAL RESEARCH COUNCIL TURKEY-TUBITAK | en_US |
dc.relation.isversionof | 10.3906/kim-1809-56 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Protic ionic liquid | en_US |
dc.subject | tribology | en_US |
dc.subject | spectroscopy | en_US |
dc.subject | quantum chemical calculation | en_US |
dc.title | Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties | en_US |
dc.type | article | en_US |
dc.relation.journal | TURKISH JOURNAL OF CHEMISTRY | en_US |
dc.contributor.department | [Karadag, Ahmet] Bartin Univ, Fac Sci, Dept Biotechnol, Bartin, Turkey -- [Karadag, Ahmet -- Akbas, Huseyin -- Korkmazer, Erdem] Gaziosmanpasa Univ, Fac Sci & Letters, Dept Chem, Tokat, Turkey -- [Karakas, Duran] Cumhuriyet Univ, Fac Sci, Dept Chem, Sivas, Turkey -- [Tekin, Kadir Cihan] Dokuz Eylul Univ, Fac Engn, Dept Met & Mat Engn, Izmir, Turkey | en_US |
dc.identifier.volume | 43 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.endpage | + | en_US |
dc.identifier.startpage | 766 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |