dc.contributor.author | Soylemez, Nazli | |
dc.contributor.author | Yabas, Ebru | |
dc.contributor.author | Bolukbasi, Serap Sahin | |
dc.contributor.author | Sulu, Mustafa | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:39:30Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:39:30Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1088-4246 | |
dc.identifier.issn | 1099-1409 | |
dc.identifier.uri | https://dx.doi.org/10.1142/S1088424618500190 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/6538 | |
dc.description | WOS: 000427932100025 | en_US |
dc.description.abstract | 4-[(4'-(Tert-butyl) phenoxy) phenoxy] phthalonitrile 1 has been prepared by the reaction of 4-(4-nitrophenoxy) phthalonitrile with 4-tertiarylbutylphenole. 4-((4'-tert-butyl) phenoxy) phenoxy tetrasubstituted metal-free 2, zinc(II) 3 and cobalt(II) 4 phthalocyanines have been prepared by tetramerization of compound 1. The synthesized phthalocyanines showed high solubility in common organic solvents such as CHCl3. All compounds were characterized by elemental analysis and H-1-NMR, C-13-NMR, UV-vis, IR spectra. Aggregation behaviors of these compounds have been investigated in different solvents (CHCl3, THF, DMF and DMSO) and different concentrations in CHCl3. The in vitro antioxidant activities of phthalocyanine compounds 2, 3 and 4 were evaluated in a series of assays involving DPPH radicals, hydroxyl radicals, superoxide radicals, singlet oxygen and hydrogen peroxide. Antioxidant activity of compound 2 was found to be higher than that of compounds 3 and 4. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | WORLD SCI PUBL CO INC | en_US |
dc.relation.isversionof | 10.1142/S1088424618500190 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Phthalocyanine | en_US |
dc.subject | synthesis | en_US |
dc.subject | aggregation | en_US |
dc.subject | antioxidant activity | en_US |
dc.title | Antioxidant activities of the new tetrasubstituted metal-free, Zn(II) and Co(II) monophthalocyanines | en_US |
dc.type | article | en_US |
dc.relation.journal | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | en_US |
dc.contributor.department | [Soylemez, Nazli -- Sulu, Mustafa] Inonu Univ, Fac Sci & Letters, Dept Chem, TR-44280 Malatya, Turkey -- [Yabas, Ebru] Cumhuriyet Univ, Adv Technol Applicat & Res Ctr, TR-58140 Sivas, Turkey -- [Bolukbasi, Serap Sahin] Cumhuriyet Univ, Fac Pharm, Dept Biochem, TR-58140 Sivas, Turkey | en_US |
dc.identifier.volume | 22 | en_US |
dc.identifier.issue | 01.Mar | en_US |
dc.identifier.endpage | 242 | en_US |
dc.identifier.startpage | 233 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |