dc.contributor.author | Hamdaoui, A. | |
dc.contributor.author | Messai, A. | |
dc.contributor.author | Benyza, N. | |
dc.contributor.author | Lanez, T. | |
dc.contributor.author | Sayin, K. | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:44:21Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:44:21Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1112-9867 | |
dc.identifier.uri | https://dx.doi.org/10.4314/jfas.v9i1.13 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/7033 | |
dc.description | WOS: 000396673900013 | en_US |
dc.description.abstract | The pyridine-2,6-dicarboxamide oxime, C7H9N5O2, was Synthesis and characterises with H-1 NMR and FTIR spectroscopy. The reaction of this ligand with nickel (II) perchlorate yielded green crystals of formula [Ni(C7H9N5O2)(2)](2+),2[ClO4](-), which crystallized in the monoclinic space group C2/c with a = 14.915(2), b = 0.895(2), c = 8.205(1) angstrom, beta = 114.69(1), and Z = 4. The complex consists of discrete cations (+II) and one perchlorate anion, the cations existing in a slightly distorted octahedral complex with bonding through the heterocyclic and oxime nitrogen atoms. The structure is held together through N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds occurring between the coordinated oxime molecules and the perchlorate counter-ion. Computational investigations of nickel(II) complex are done by using M062X method with 6-31+G(d)(LANL2DZ) basis set in vacuo. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | UNIV EL OUED, FAC SCIENCE & TECHNOLOGY | en_US |
dc.relation.isversionof | 10.4314/jfas.v9i1.13 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Oxime complexe | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Hydrogen-bonding graph-set | en_US |
dc.subject | DFT | en_US |
dc.subject | M062X method | en_US |
dc.subject | 6-31+G(d)(LANL2DZ) basis | en_US |
dc.title | SYNTHESIS, CRYSTAL STRUCTURES, HYDROGEN BONDING GRAPH-SETS AND THEORETICAL STUDIES OF NICKEL ( plus II) CO-ORDINATIONS WITH PYRIDINE-2,6-DICARBOXAMIDE OXIME | en_US |
dc.type | article | en_US |
dc.relation.journal | JOURNAL OF FUNDAMENTAL AND APPLIED SCIENCES | en_US |
dc.contributor.department | [Hamdaoui, A. -- Messai, A. -- Benyza, N.] Univ Abbes Laghrour, Lab Ingn & Sci Mat Avances ISMA, Inst Sci & Technol, Khenchela 40000, Algeria -- [Benyza, N. -- Lanez, T.] Univ El Oued, Fac Exact Sci, VTRS Lab, POB 789, El Oued 39000, Algeria -- [Sayin, K.] Cumhuriyet Univ, Inst Sci, Dept Chem, TR-58140 Sivas, Turkey | en_US |
dc.identifier.volume | 9 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.endpage | 205 | en_US |
dc.identifier.startpage | 183 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |