dc.contributor.author | Celik, Ismail | |
dc.contributor.author | Akkurt, Mehmet | |
dc.contributor.author | Jarrahpour, Aliasghar | |
dc.contributor.author | Rad, Javad Ameri | |
dc.contributor.author | Celik, Omer | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:56:20Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:56:20Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.uri | https://dx.doi.org/10.1107/S2056989015001425 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/7958 | |
dc.description | WOS: 000369971500055 | en_US |
dc.description | PubMed ID: 25878867 | en_US |
dc.description.abstract | In the title solvated compound, C28H19N2O4 center dot C2H6OS, the central beta-lactam ring is almost planar (r.m.s. deviation = 0.002 angstrom). It makes dihedral angles of 1.92 (11), 83.23 (12) and 74.90 (10)degrees with the methoxy-and chlorophenyl rings and the ring plane of the 1H-benzo[de]isoquinoline-1,3(2H)-dione group [maximum deviation = 0.089 (1)], respectively. An intramolecular C-H center dot center dot center dot O hydrogen bond closes an S(6) ring and helps to establish the near coplanarity of the beta-lactam and methoxybenzene rings. In the crystal, the components are linked by C-H center dot center dot center dot O hydrogen bonds, C-H center dot center dot center dot pi interactions and aromatic pi-pi stacking interactions [centroid-to-centroid distances = 3.6166 (10) and 3.7159 (10) angstrom], resulting in a three-dimensional network, The dimethyl sulfoxide solvent molecule is disordered over two sets of sites in a 0.847 (2):0.153 (2) ratio. | en_US |
dc.description.sponsorship | Shiraz University Research Council [93-GR-SC-23] | en_US |
dc.description.sponsorship | The authors are indebted to the X-ray laboratory of Dicle University Scientific and Technological Applied and Research Center, Diyarbakir, Turkey, for use of the X-ray diffractometer. AJ and JAR thank the Shiraz University Research Council for financial support (grant No. 93-GR-SC-23). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | INT UNION CRYSTALLOGRAPHY | en_US |
dc.relation.isversionof | 10.1107/S2056989015001425 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | crystal structure | en_US |
dc.subject | beta-lactam ring | en_US |
dc.subject | 1H-benzo[de]isoquinoline-1,3(2H)-dione group | en_US |
dc.subject | disorder | en_US |
dc.subject | azetidin-2-ones | en_US |
dc.title | Crystal structure of 2-[4-(4-chlorophenyl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]benzo[de]isoquinoline-1,3-dione dimethyl sulfoxide monosolvate | en_US |
dc.type | article | en_US |
dc.relation.journal | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | en_US |
dc.contributor.department | [Celik, Ismail] Cumhuriyet Univ, Fac Arts & Sci, Dept Phys, TR-06532 Sivas, Turkey -- [Akkurt, Mehmet] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkey -- [Jarrahpour, Aliasghar -- Rad, Javad Ameri] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran -- [Celik, Omer] Dicle Univ, Dept Phys, Fac Educ, TR-21280 Diyarbakir, Turkey -- [Celik, Omer] Dicle Univ, Sci & Technol Applicat & Res Ctr, TR-21280 Diyarbakir, Turkey | en_US |
dc.contributor.authorID | Celik, Omer -- 0000-0002-3314-6132 | en_US |
dc.identifier.volume | 71 | en_US |
dc.identifier.endpage | U587 | en_US |
dc.identifier.startpage | O129 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |