dc.contributor.author | Celik, Ismail | |
dc.date.accessioned | 2019-07-27T12:10:23Z | |
dc.date.accessioned | 2019-07-28T09:59:26Z | |
dc.date.available | 2019-07-27T12:10:23Z | |
dc.date.available | 2019-07-28T09:59:26Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1074-1542 | |
dc.identifier.uri | https://dx.doi.org/10.1007/s10870-013-0433-y | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/8652 | |
dc.description | WOS: 000321969600008 | en_US |
dc.description.abstract | The crystal structure of 2',3',3'-tribromo-2',3'-dihydrospiro[1,3-dioxolane-2,1'-indene], (C11H9Br3O2 ), has been determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in the monoclinic space group P2(1)/n with unit cell parameters: a = 8.9799(4), b = 11.3368(8), c = 12.4233(9) , beta = 94.938(4)A degrees, V = 1260.04(14) (3), Z = 4. The cyclopentane ring fused to the benzene ring adopts an envelope conformation with C11 at the tip of the envelope. The crystal structure is stabilized by C-H center dot center dot center dot Br and C-H center dot center dot center dot O interactions. The C atoms of the CH (2) groups of the 1,3-dioxolane ring, are disordered over two sites with an occupancy ratio of 0.62(7):0.38(7). A semiempirical quantum-mechanical calculation was carried out using the CNDO approximation. The crystal structure of 2',3',3'-tribromo-2',3'-dihydrospiro[1,3-dioxolane-2,1'-indene], (C11H9Br3O2 ), has been determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in the monoclinic space group P21/n with unit cell parameters: a = 8.9799(4), b = 11.3368(8), c = 12.4233(9) , beta = 94.938(4)A degrees, V = 1260.04(14) (3), Z = 4. The cyclopentane ring fused to the benzene ring adopts an envelope conformation with C11 at the tip of the envelope. The crystal structure is stabilized by C-H center dot center dot center dot Br and C-H center dot center dot center dot O interactions. The C atoms of the CH (2) groups of the 1,3-dioxolane ring, are disordered over two sites with an occupancy ratio of 0.62(7):0.38(7). A semiempirical quantum-mechanical calculation was carried out using the CNDO approximation. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | SPRINGER/PLENUM PUBLISHERS | en_US |
dc.relation.isversionof | 10.1007/s10870-013-0433-y | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Single-crystal X-ray diffraction | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Hydrogen bonding | en_US |
dc.subject | CNDO | en_US |
dc.title | Synthesis, Crystal and Molecular Structure of 2',3',3'-Tribromo-2',3'-dihydrospiro[1,3-dioxolane-2,1'-indene] | en_US |
dc.type | article | en_US |
dc.relation.journal | JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | en_US |
dc.contributor.department | Cumhuriyet Univ, Dept Phys, Fac Sci, TR-58140 Sivas, Turkey | en_US |
dc.identifier.volume | 43 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.endpage | 393 | en_US |
dc.identifier.startpage | 390 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |