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1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate

Date

2010

Author

Akkurt, Mehmet
Celik, Ismail
Kucukbay, Hasan
Sireci, Nihat
Buyukgungor, Orhan

Metadata

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Abstract

The title compound, C(18)H(23)N(2)Si(+)center dot Cl(-)center dot H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) angstrom, and makes an angle of 74.80 (12)degrees with the phenyl ring. The crystal packing is stabilized by O-H center dot center dot center dot Cl, C-H center dot center dot center dot Cl, C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions between symmetry-related molecules together with pi-pi stacking interactions between the imidazolium and benzene rings [centroid-centroid distance = 3.5690 (15) angstrom] and between the benzene rings [centroid-centroid distance = 3.7223 (14) angstrom].

Source

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Volume

66

URI

https://dx.doi.org/10.1107/S1600536810024128
https://hdl.handle.net/20.500.12418/9833

Collections

  • Makale Koleksiyonu [5200]
  • Makale Koleksiyonu [5745]
  • Öksüz Yayınlar Koleksiyonu - WoS [6162]



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