Ultrasonic-assisted dispersive liquid-liquid microextraction based on hydrophilic deep eutectic solvents: Application to lead and cadmium monitoring in water and food samples

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dc.authoridTuzen, Mustafa/0000-0001-8522-6620
dc.contributor.authorAltunay, Nail
dc.contributor.authorTuzen, Mustafa
dc.contributor.authorMogaddam, Mohammad Reza Afshar
dc.date.accessioned2024-10-26T18:09:28Z
dc.date.available2024-10-26T18:09:28Z
dc.date.issued2022
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractA green and innovative ultrasonic-assisted dispersive liquid-liquid microextraction using hydrophilic deep eutectic solvents (UA-HDES-DLLME) was developed for the selective and simultaneous extraction and enrichment of Pb (II) and Cd (II) in water and food samples for flame atomic absorption spectrometry. Several natural deep eutectic solvents (NADES) were used for the preparation of six different HDES and methyl violet was used as chelating reagent. Effective parameters such as pH, sonication time, methyl violet amount, DES type, dispersive solvent types, etc were optimized. Relative standard deviation (RSD) and preconcentration factor (PF) were 4.0% and 80. Low limits of detection (LOD, 1.3 ng mL(-1) for Pb (II) and 0.33 ng mL(-1) for Cd (II)) and quantification (LOQ, 4.0 ng mL(-1) for Pb (II) and 1.0 ng mL(-1) for Cd (II)) were found. The method accuracy was confirmed with analyses of certified reference materials.
dc.description.sponsorshipTurkish Academy of Sciences (TUBA)
dc.description.sponsorshipDr. Mustafa Tuzen would like to thank the Turkish Academy of Sciences (TUBA) for partial support.
dc.identifier.doi10.1080/19440049.2022.2130997
dc.identifier.endpage1973
dc.identifier.issn1944-0049
dc.identifier.issn1944-0057
dc.identifier.issue12
dc.identifier.pmid36287207
dc.identifier.startpage1963
dc.identifier.urihttps://doi.org/10.1080/19440049.2022.2130997
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30127
dc.identifier.volume39
dc.identifier.wosWOS:000875036300001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofFood Additives and Contaminants Part A-Chemistry Analysis Control Exposure & Risk Assessment
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectUltrasound-assisted dispersive liquid-liquid microextraction
dc.subjecthydrophilic deep eutectic solvents
dc.subjectCadmium and lead
dc.subjectwater and food samples
dc.titleUltrasonic-assisted dispersive liquid-liquid microextraction based on hydrophilic deep eutectic solvents: Application to lead and cadmium monitoring in water and food samples
dc.typeArticle

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