Ultrasonic-assisted dispersive liquid-liquid microextraction based on hydrophilic deep eutectic solvents: Application to lead and cadmium monitoring in water and food samples
dc.authorid | Tuzen, Mustafa/0000-0001-8522-6620 | |
dc.contributor.author | Altunay, Nail | |
dc.contributor.author | Tuzen, Mustafa | |
dc.contributor.author | Mogaddam, Mohammad Reza Afshar | |
dc.date.accessioned | 2024-10-26T18:09:28Z | |
dc.date.available | 2024-10-26T18:09:28Z | |
dc.date.issued | 2022 | |
dc.department | Sivas Cumhuriyet Üniversitesi | |
dc.description.abstract | A green and innovative ultrasonic-assisted dispersive liquid-liquid microextraction using hydrophilic deep eutectic solvents (UA-HDES-DLLME) was developed for the selective and simultaneous extraction and enrichment of Pb (II) and Cd (II) in water and food samples for flame atomic absorption spectrometry. Several natural deep eutectic solvents (NADES) were used for the preparation of six different HDES and methyl violet was used as chelating reagent. Effective parameters such as pH, sonication time, methyl violet amount, DES type, dispersive solvent types, etc were optimized. Relative standard deviation (RSD) and preconcentration factor (PF) were 4.0% and 80. Low limits of detection (LOD, 1.3 ng mL(-1) for Pb (II) and 0.33 ng mL(-1) for Cd (II)) and quantification (LOQ, 4.0 ng mL(-1) for Pb (II) and 1.0 ng mL(-1) for Cd (II)) were found. The method accuracy was confirmed with analyses of certified reference materials. | |
dc.description.sponsorship | Turkish Academy of Sciences (TUBA) | |
dc.description.sponsorship | Dr. Mustafa Tuzen would like to thank the Turkish Academy of Sciences (TUBA) for partial support. | |
dc.identifier.doi | 10.1080/19440049.2022.2130997 | |
dc.identifier.endpage | 1973 | |
dc.identifier.issn | 1944-0049 | |
dc.identifier.issn | 1944-0057 | |
dc.identifier.issue | 12 | |
dc.identifier.pmid | 36287207 | |
dc.identifier.startpage | 1963 | |
dc.identifier.uri | https://doi.org/10.1080/19440049.2022.2130997 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/30127 | |
dc.identifier.volume | 39 | |
dc.identifier.wos | WOS:000875036300001 | |
dc.identifier.wosquality | Q2 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | PubMed | |
dc.language.iso | en | |
dc.publisher | Taylor & Francis Ltd | |
dc.relation.ispartof | Food Additives and Contaminants Part A-Chemistry Analysis Control Exposure & Risk Assessment | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | Ultrasound-assisted dispersive liquid-liquid microextraction | |
dc.subject | hydrophilic deep eutectic solvents | |
dc.subject | Cadmium and lead | |
dc.subject | water and food samples | |
dc.title | Ultrasonic-assisted dispersive liquid-liquid microextraction based on hydrophilic deep eutectic solvents: Application to lead and cadmium monitoring in water and food samples | |
dc.type | Article |