dc.contributor.author | Akbulut Söylemez, Meshude | |
dc.contributor.author | Kaplan Can, Hatice | |
dc.contributor.author | Bağda, Esra | |
dc.contributor.author | Barsbay, Murat | |
dc.date.accessioned | 2023-06-22T13:09:52Z | |
dc.date.available | 2023-06-22T13:09:52Z | |
dc.date.issued | October 2022 | tr |
dc.identifier.citation | Meshude Akbulut Soylemez ¨ a
, Hatice Kaplan Can a
, Esra Bagda ˘ b
, Murat Barsbay a,*
a Department of Chemistry, Hacettepe University, Beytepe, 06800, Ankara, Turkey b Analytical Chemistry Division, Faculty of Pharmacy, Sivas Cumhuriyet University, 58140, Sivas, Turkey | tr |
dc.identifier.uri | https://hdl.handle.net/20.500.12418/13986 | |
dc.description.abstract | Despite technical and methodological advances, the selective separation of antibiotics from aqueous media remains a challenge. In this work, a novel molecularly imprinting polymer (MIP) with specific recognition sites was constructed by radiation-induced RAFT-mediated graft copolymerization of methacrylic acid (MAA) and ethylene glycol dimethacrylate (EGDMA) from PE/PP nonwoven fabric for tetracycline hydrochloride (TC) removal. Binding isotherm and kinetics were found to follow Freundlich and pseudo-second-order model, respectively. The as-synthesized molecularly-imprinted fabric exhibited excellent binding performance towards TC, with the maximum adsorption capacity and imprinting factor of 46.7 mg g−1 and 3.6, respectively. Moreover, it removed approximately 95% of TC from the aqueous media, also performed well in real environmental samples. For comparison purposes, MIPs obtained with conventional grafting performed significantly lower than those attained by RAFT-mediated grafting. After ten consecutive adsorption and desorption cycles, the fabric-based molecularly-imprinted material retained excellent stability and reusability with a performance loss of only 3.6%, which could facilitate its potential application on an industrial scale. | tr |
dc.language.iso | eng | tr |
dc.rights | info:eu-repo/semantics/embargoedAccess | tr |
dc.subject | Molecularly imprinting polymer (MIP)RAFT-Mediated graft copolymerizationRadiation-induced graftingTetracycline removal | tr |
dc.title | A porous fabric-based molecularly imprinted polymer for specific recognition of tetracycline by radiation-induced RAFT-mediated graft copolymerization | tr |
dc.type | article | tr |
dc.contributor.department | Eğitim Bilimleri Enstitüsü | tr |
dc.relation.publicationcategory | Rapor | tr |