Kimya Bölümü Makale Koleksiyonu: Recent submissions
Now showing items 1-20 of 166
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A pH-dependent CT sensitive method for detection of trace Mn in milk by UV-spectrophotometry
(1 Septembe)In this study, a new method was developed for the extractive pre-concentration/detection of trace Mn in milk prior to analysis by UV-spectrophotometry. The method is based on the pH-controlled intra-ligand charge transfer ... -
Novel amide- and imide-co-polymers modified with sulfathiazole as efficient chelator for selective extraction, pre-concentration and determination of trace inorganic antimony (as Sb(III)) from edible vegetable oils by ultrasound assisted-cloud point extraction coupled to micro-volume UV-spectrophotometry
(Elsevier, 22 Septemb)The study described the synthesis, characterization, and application of newly prepared sulfathiazole-modified amide/imide co-polymers for the extraction of trace Sb(III) from edible vegetable oils. The method was based on ... -
A new pre-concentration procedure based on poly(styrene-co-maleamide and imide) copolymers modified with 2-hydrazinobenzothiazole prior to spectrophotometric monitoring of inorganic as (as As(III)) in edible vegetable oils
(Elsevier, 27 Decembe)This study describes the development of 2-hydrazinobenzothiazole modified-amide/imide co-polymers for the extraction/pre-concentration of trace As(III), from edible vegetable oils. Their characterization was realized by ... -
Molecular insights into the corrosion inhibition mechanism of omeprazole and tinidazole: a theoretical investigation
(2023)In many studies published in recent years, corrosion scientists proved that various drug molecules can exhibit high inhibition performance against the corrosion of metal surfaces and alloys. This study presents the adsorption ... -
Molecular docking and A DFT study on the antiradical activity of naringenin and hesperetin with nitric oxide, peroxy, and methoxy radicals
(2023)Naturally occurring flavonoids, naringenin (N) and hesperetin (H), weretheoretically investigated for their ability to scavenge nitric oxide, peroxy,and methoxy radicals in gas, water, and benzene solvent ... -
Chemical composition, antimicrobial activities, and molecular docking studies of Turkish propolis ethanol extract
(CAAS Agricultural Journals, 2023)The purpose of the present study was to investigate the antimicrobial effect of propolis ethanol extract collected from the Tarsus district of Mersin province, Kilis province, Yayladagi district of Hatay province in southern ... -
Synthesis, docking studies, in vitro cytotoxicity evaluation and DNA damage mechanism of new tyrosine-based tripeptides
(Wiley, 2023)Peptides are one of the leading groups of compounds that have been the subject of a great deal of biological research and still continue to attract researchers' attention. In this study, a series of tripeptides based on ... -
Bromination and conversion of tetrahydro-1H-indene to bisoxirane with a new approach: synthesis, structural characterization by spectroscopic and theoretical methods, and biological analysis supported by DFT and docking
(TÜBİTAK, 2023)In this study, a new method for synthesizing diepoxides is proposed. Tetrahydroindene 1 was brominated with NBS in the presence of LiClO4 and acetic acid, resulting in the formation of dibromodiacetate derivatives 2 and ... -
Equilibrium and Computational Chemical Modelling Studies for the Removal of Methyl Orange and Methyl Red Dyes from Water Using Modified Silica Resin
(Taylor & Francis, 2023)This study describes the removal of methyl orange (MO) and methyl red (MR) dyes from water samples using morpholinomethylcalix[4]arene immobilised silica (MIS) resin. The silica surface has been modified by p-morpholinom ... -
Modeling, spectroscopic structural properties of platinum-II complexes of 2-((phenylimino)methyl)phenolate-based ligands and research of nonlinear optical, organic light emitting diode and solar cell performances
(Elsevier, 2023)The hypothetical Pt(B1)2, Pt(B2)2 and Pt(B3)2 complexes were modeled. B1, B2 and B3 are Schiff bases, 2-((phenylimino)methyl)phenolate, 4-methyl-2-((phenylimino)methyl)phenolate and 4-nitro-2-((phenylimino)methyl)phenolate, ... -
In Silico and In Vitro Studies of Novel Azomethines on DNA Repair Genes in Gastric Cell Lines
(MDPI, 2023)We herein report the determination of the cytotoxic activity and expression profiles of some DNA repair genes of newly synthesized azomethines in the gastric cancer cell line (AGS). The studied novel compounds were synthesized ... -
Analysis of boronic acids containing amino ferrocene by DFT approach and in silico studies
(Elsevier, 2023)The synthesized (2)-(6) complexes and (2′)-(6′) hypothetical complexes formed by attached boranic acid esters were optimized at the DFT-B3LYP/GEN level. The structural and spectroscopic properties (IR, 1HNMR , 13CNMR ) of ... -
Investigation of substituent effect on rhenium complexes by DFT methods: Structural analysis, IR spectrum, quantum chemical parameter, NLO and OLED properties, molecular docking
(Elsevier, 2023)For the synthesized 9b, 9c and 9d complexes, hypothetical complexes were formed by adding electron-withdrawing (NO2) and electron-donating (NH2) groups. Benchmark analysis was performed using the bond lengths of the ... -
Equilibrium and DFT modeling studies for the biosorption of Safranin O dye from water samples using Bacillus subtilis biosorbent.
(Elsevier, 2023)Current study deals with the biosorption of Safranin O dye from water by using high potential Bacillus subtilis biosorbent material. The presence of functional groups and surface morphology of biosorbent was analyzed by ... -
A series of phenanthroline-imine compounds: Computational, OLED properties and fluorimetric sensing of nitroaromatic compounds.
(Elsevier, 2023)In this study, Schiff base compounds (1–5) were synthesized by the reaction of 5-amino-1,10-phenanthroline with various aldehydes. The molecular structures of the synthesized compounds were characterized by FT-IR, 1H/13C ... -
Crystal structure, Hirshfeld surface analysis, computational and antifungal studies of dihydropyrimidines on the basis of salicylaldehyde derivatives
(2023)We herein reported the synthesis of dihydropyrimidines 1 and 2 on the basis of nitro and brominated salicylaldehyde derivatives by Biginelli reaction in microwave conditions in the presence of cheap low toxic copper ... -
Eaton's reagent is an alternative of PPA: Solvent free synthesis, molecular docking and ADME studies of new angular and linear carbazole based naphtho naphthyridines
(2023)An approach towards the preparation of novel angular and linear carbazole based naphtho naphthyridines are described in good yields. From schematic study on the condensation of 4-chloro-2- methylbenzo[h]quinoline and ... -
New azo-azomethine based copper(II) and zinc(II) complexes: Synthesis, electrochemistry, photoluminescence properties, density functional theory calculations and molecular docking
(2023)A new bidentate azo-azomethine ligand 2-{(E)-[(3,4-dimethylphenyl) imino]methyl}-4-[(E)-(4-ethylphenyl)diazenyl] phenol (2) and its copper(II) and zinc(II) complexes (3) and (4) were synthesized and characterized by elemental ... -
[Cu 2 (ox)(dien) 2 ](NO 3 ) 3 , a precursor for preparation of CuO nanoparticles: Synthesis, structural, Hirshfeld surface analyses, and physico-chemical investigations
(2023)[C u 2 ( ox )( dien ) 2 ](NO 3 ) 3 with (ox = oxalate, dien = diethylenetriamine) has been synthesized and charac- terized by single-crystal X-ray diffraction as well as FTIR and UV–Vis spectroscopic techniques. The complex ... -
Synthesis, nanostructuring and in silico studies of a new imine bond containing a macroheterocycle as a promising PBP-2a non-b-lactam inhibitor
(2023)This study is devoted to the synthesis of a 40-membered macroheterocycle with its further nanostructuring by magnetite nanoparticles. The mentioned macroheterocycle was synthesized by the [2+2] cyclocondensation of the ...
