Air-assisted liquid-liquid microextraction of total 3-monochloropropane-1,2-diol from refined edible oils based on a natural deep eutectic solvent and its determination by gas chromatography-mass spectrometry

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dc.authoridAfshar mogaddam, Mohammad reza/0000-0003-1144-4523
dc.authoridFarajzadeh, Mir Ali/0000-0003-3746-0011
dc.contributor.authorNemati, Mahboob
dc.contributor.authorAltunay, Nail
dc.contributor.authorTuzen, Mustafa
dc.contributor.authorFarajzadeh, Mir Ali
dc.contributor.authorNabil, Ali Akbar Alizadeh
dc.contributor.authorLotfipour, Farzaneh
dc.contributor.authorMogaddam, Mohammad Reza Afshar
dc.date.accessioned2024-10-26T18:11:08Z
dc.date.available2024-10-26T18:11:08Z
dc.date.issued2021
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractIn this paper, a fast, sensitive, and selective sample preparation procedure was presented for the determination of 3-monochloropropane-1,2-diol (3-MCPD) in refined edible oils using gas chromatographymass spectrometry. In this method, firstly, the sample lipids and analyte fatty esters are saponified by sodium hydroxide under sonication. After that the analyte was derivatized using phenylboronic acid (as the derivatization agent) and the obtained derivative was extracted during an air-assisted liquid-liquid microextraction procedure (AALLME). Six different deep eutectic solvents (DESs) were prepared as the extraction solvents and the most effective extraction for 3-MCPD was obtained in the presence of a natural DES (NDES) consisting of choline chloride (ChCl)-acetic acid (AcOH). Important variables such as sodium hydroxide concentration and volume, sonication time, temperature, extraction solvent type and volume, and phenylboronic acid concentration and volume have been optimized. Using the optimum conditions, broad linear range (0.88-1000 ng g(-1)), suitable coefficient of determination (0.995), and low limits of detection (0.26 ng g(-1)) and quantification (0.88 ng g(-1)) were obtained. Relative standard deviations for intra- (n=8) and inter-day (n=6) precisions at a concentration of 5 ng g(-1) were 2.6 and 3.2%, respectively. The developed method has been successfully applied to 3-MCPD determination in refined edible oil samples including sunflower, corn, and canola oils. (C) 2021 Elsevier B.V. All rights reserved.
dc.description.sponsorshipResearch Council of the Tabriz University of Medical Science
dc.description.sponsorshipThe authors thank the Research Council of the Tabriz University of Medical Science for financial support.
dc.identifier.doi10.1016/j.chroma.2021.462559
dc.identifier.issn0021-9673
dc.identifier.issn1873-3778
dc.identifier.pmid34571280
dc.identifier.scopus2-s2.0-85115661503
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.chroma.2021.462559
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30536
dc.identifier.volume1656
dc.identifier.wosWOS:000701976400001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Chromatography A
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectNatural deep eutectic solvent
dc.subject3-Monochloropropane-1, 2-diol
dc.subjectEdible oil
dc.subjectGas chromatography
dc.subjectMass spectrometry
dc.subjectAir-assisted liquid-liquid microextraction
dc.titleAir-assisted liquid-liquid microextraction of total 3-monochloropropane-1,2-diol from refined edible oils based on a natural deep eutectic solvent and its determination by gas chromatography-mass spectrometry
dc.typeArticle

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