Novel cucurbit[6]uril-based [3]rotaxane supramolecular ionic liquid as a green and excellent corrosion inhibitor for the chemical industry
Küçük Resim Yok
Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The corrosion of steel materials in alkaline-saline media is the largest problem in industry. Economical and environmentally friendly corrosion inhibitors are crucial for corrosion protection. The present work is the first to introduce a novel cucurbit[6]uril-based [3]rotaxane supramolecular ionic liquid (CB6-based [3]rotaxane) as a green and efficient corrosion inhibitor for the chemical industry. The correlation between the supramolecular ionic liquid system and inhibition behavior was studied first. The inhibition characteristics of CB6-based [3] rotaxane in 1 M OH- + 1 M Cl- solution were first fully investigated by thermodynamic, gravimetric, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), electrochemical noise (EN), cyclic voltammetry (CV), density functional theory (DFT), molecular dynamics (MD) simulation, scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX) methods. The experimental results confirmed that CB6-based [3]rotaxane exhibited excellent corrosion resistance, and its inhibition efficiency was 97.97% at 100 mg/L and 0.032 mM. The electrochemical results suggested that (i) CB6-based [3]rotaxane was a mixed-type corrosion inhibitor with anodic dominance; (ii) the supramolecular part of selected ionic liquid is responsible for notably blocks the charge transfer process on the metal surface. The theoretical findings correlated well with the experimental results and revealed that the protonated form of this supramolecular structure exhibited better performance than its neutral form. MD simulations results suggested that the bond length of the Fe(surface)inhibitor (3.127 angstrom) is less than 3.5 angstrom, which indicates that chemisorption is dominant in the investigated adsorption system. Molecular electrostatic potential analysis confirmed that the studied ionic liquidsupramolecular system contained most favorable nucleophilic centers, which are responsible for excellent inhibition performance.
Açıklama
Anahtar Kelimeler
Corrosion inhibitor, Ionic liquids, Alkaline-saline solution, Cucurbit[6]uril, Rotaxane
Kaynak
Colloids and Surfaces A-Physicochemical and Engineering Aspects
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
633
