Structural, spectral, DFT and biological studies on macrocyclic mononuclear ruthenium (II) complexes

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dc.authoridC, Kamal -- 0000-0002-6097-665X; Muthukkumar, Dr Manickam -- 0000-0003-4318-6485en_US
dc.contributor.authorMuthukkumar, M.
dc.contributor.authorKamal, C.
dc.contributor.authorVenkatesh, G.
dc.contributor.authorKaya, C.
dc.contributor.authorKaya, S.
dc.contributor.authorEnoch, Israel V. M. V.
dc.contributor.authorVennila, P.
dc.contributor.authorRajavel, R.
dc.date.accessioned2019-07-27T12:10:23Z
dc.date.accessioned2019-07-28T09:39:56Z
dc.date.available2019-07-27T12:10:23Z
dc.date.available2019-07-28T09:39:56Z
dc.date.issued2017
dc.department[Muthukkumar, M.] Selvam Arts & Sci Coll, Dept Chem, Namakkal, Tamil Nadu, India -- [Kamal, C. -- Venkatesh, G.] VSA Grp Inst, Dept Chem, Salem, Tamil Nadu, India -- [Kaya, C. -- Kaya, S.] Cumhuriyet Univ, Dept Chem, TR-58140 Sivas, Turkey -- [Enoch, Israel V. M. V.] Sch Karunya Univ, Dept Chem, Coimbatore, Tamil Nadu, India -- [Vennila, P.] Thiruvalluvar Govt Arts Coll, Dept Chem, Rasipuram 637401, India -- [Rajavel, R.] Periyar Univ, Dept Chem, Salem 636011, Tamil Nadu, Indiaen_US
dc.description.abstractMacrocyclic mononuclear ruthenium (II) complexes have been synthesized by condensation method [Ru (L1, L2, L3) Cl-2] L-1 = (C-36 H-31 N-9), L-2= (C42H36N8), L-3= (C32H32 N-8)]. These ruthenium complexes have been established by elemental analyses and spectroscopic techniques (Fourier transform infrared spectroscopy (FT-IR), H-1-nuclear magnetic resonance (NMR), C-13-NMR and Electrospray ionization mass spectrometry (ESI-MS)). The coordination mode of the ligand has been confirmed and the octahedral geometry around the ruthenium ion has been revealed. Binding affinity and binding mode of ruthenium (II) complexes with Bovine serum Albumin (BSA) have been characterized by Emission spectra analysis. UV-Visible and fluorescence spectroscopic techniques have also been utilized to examine the interaction between ligand and its complexes L1, L2, & L3 with BSA. Chemical parameters and molecular structure of Ru (II) complexes L1H, L2H, & L3H have been determined by DFT coupled with B3LYP/6-311G** functional in both the gaseous and aqueous phases. (C) 2017 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2017.06.132en_US
dc.identifier.endpage514en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85021641035en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage502en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2017.06.132
dc.identifier.urihttps://hdl.handle.net/20.500.12418/6606
dc.identifier.volume1147en_US
dc.identifier.wosWOS:000408299900057en_US
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMononuclear rutheniumen_US
dc.subjectBovine serum albuminen_US
dc.subjectDensity functional theoryen_US
dc.subjectIRen_US
dc.subjectNMRen_US
dc.titleStructural, spectral, DFT and biological studies on macrocyclic mononuclear ruthenium (II) complexesen_US
dc.typeArticleen_US

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