Adsorption study of N (-benzo[d]thiazol-2-yl)-1-(thiophene-2-yl) methanimine at mild steel/aqueous H2SO4 interface

Basit Öğe Kaydı
dc.authoridSingh, Ashish/0000-0001-8076-0816
dc.authoridMarzouki, Riadh/0000-0002-2502-2164
dc.authoridSingh, Manjeet/0000-0002-9195-0532
dc.contributor.authorSingh, Ashish Kumar
dc.contributor.authorSingh, Manjeet
dc.contributor.authorThakur, Sanjeeve
dc.contributor.authorPani, Balaram
dc.contributor.authorKaya, Savas
dc.contributor.authorEL Ibrahimi, Brahim
dc.contributor.authorMarzouki, Riadh
dc.date.accessioned2024-10-26T18:11:30Z
dc.date.available2024-10-26T18:11:30Z
dc.date.issued2022
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractThis study reports microwave (MW) assisted synthesis of N (-benzo[d]thiazol-2-yl)-1-(thiophene-2-yl) methanimine (BTTM) in reasonably good yield and purity. The synthesized compound (BTTM) has been characterized by elemental analysis, IR and 1H NMR spectroscopy and examined for its corrosion inhibition activity for mild steel in aqueous H2SO4 medium using gravimetric and different electrochemical methods. The corrosion inhibition study was also performed at different temperatures to understand the effect of temperature on corrosion inhibiting potential of BTTM. The metal protecting ability of BTTM in acid solution was further examined by surface analyses; X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and contact angle measurement. The surface analyses reveal that the BTTM adsorbed on mild steel (MS) surface following ElAwady isotherm. Theoretical studies, viz. molecular orbital analysis and molecular dynamic (MD) modelling were also conducted to understand the inhibition mechanism completely.
dc.description.sponsorshipKing Khalid University [11/1-349/2022/FIN -B/]; [R.G.P.2/224/43]
dc.description.sponsorshipAuthors are thankful to their Institutions for providing platform to carry out this work. We are also thankful to our friends and colleagues who assisted this research work directly or indirectly. Author Manjeet Singh acknowledges the financial support received in the form of Research Promotion Grant MZU (11/1-349/2022/FIN -B/) to provide his contribution in this research. Authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding theoretical work of this study through research group under grant number R.G.P.2/224/43.
dc.identifier.doi10.1016/j.surfin.2022.102169
dc.identifier.issn2468-0230
dc.identifier.scopus2-s2.0-85133816774
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.surfin.2022.102169
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30685
dc.identifier.volume33
dc.identifier.wosWOS:000829331300002
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofSurfaces and Interfaces
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectMicrowave
dc.subjectElectrophilicity
dc.subjectAFM
dc.subjectEIS
dc.subjectPolarization
dc.subjectMolecular orbital analysis
dc.titleAdsorption study of N (-benzo[d]thiazol-2-yl)-1-(thiophene-2-yl) methanimine at mild steel/aqueous H2SO4 interface
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu