The Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric, Electrochemical, SEM-EDS, and Quantum Chemical Calculations

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dc.authoridBILGICLI, Ahmet Turgut/0000-0002-4144-7357
dc.authoridYarasir, Meryem Nilufer/0000-0002-7327-7137
dc.authoridAKIN, mustafa/0000-0003-4268-6891
dc.authoridGunsel, Armagan/0000-0003-1965-1017
dc.authoridTUZUN, BURAK/0000-0002-0420-2043
dc.authoridArabaci, Gulnur/0000-0002-1190-5695
dc.contributor.authorAkin, Mustafa
dc.contributor.authorGunsel, Armagan
dc.contributor.authorBilgicli, Ahmet T.
dc.contributor.authorTuzun, Burak
dc.contributor.authorArabaci, Gulnur
dc.contributor.authorSaki, Neslihan
dc.contributor.authorYarasir, M. Nilufer
dc.date.accessioned2024-10-26T18:09:05Z
dc.date.available2024-10-26T18:09:05Z
dc.date.issued2020
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractCorrosion inhibition effects of water-soluble peripheral substituted cobalt, copper and zinc metallophthalocyanines (CoPc(1), CuPc(2)and ZnPc(3)) on the copper metal in 0.1 N HCl were investigated by using gravimetric, electrochemical, SEM-EDS analysis and quantum chemical calculations. On the electrochemical investigations and gravimetric analysis the highest inhibitor efficiency was obtained with CoPc(1)at 1 x 10(-2)mol/L concentration. SEM-EDS results indicated parallel results and oxygen atom content increased in the order of ZnPc(3), CuPc(2)and CoPc(1). According to the quantum chemical calculations, following corrosion inhibition efficiency ranking was obtained: CoPc(1)> CuPc(2)> ZnPc(3).
dc.description.sponsorshipResearch Fund of Sakarya University [Hzdep-2019-5-19-56]
dc.description.sponsorshipThis work was supported by The Research Fund of Sakarya University (Project Number: Hzdep-2019-5-19-56). This research was made possible by TUBITAK ULAKBIM, High Performance and Grid Computing Center (TR-Grid e-Infrastructure).
dc.identifier.doi10.1134/S207020512003003X
dc.identifier.endpage618
dc.identifier.issn2070-2051
dc.identifier.issn2070-206X
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85088895656
dc.identifier.scopusqualityQ2
dc.identifier.startpage609
dc.identifier.urihttps://doi.org/10.1134/S207020512003003X
dc.identifier.urihttps://hdl.handle.net/20.500.12418/29947
dc.identifier.volume56
dc.identifier.wosWOS:000556021800021
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofProtection of Metals and Physical Chemistry of Surfaces
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectmetallophthalocyanines
dc.subjectcopper
dc.subjectacid corrosion
dc.subjectSEM
dc.subjectEIS
dc.titleThe Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric, Electrochemical, SEM-EDS, and Quantum Chemical Calculations
dc.typeArticle

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