New Bi-Nuclear Nickel(II) Complex-Based Salen Schiff Base: Synthesis, Crystal Structure, Spectroscopic, Thermal, and Electrical Investigations

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dc.authoridBAKHOUCH, Mohamed/0000-0003-0732-6524
dc.authoridEl Ammari, Lahcen/0000-0001-7980-974X
dc.authoridSaadi, Mohamed/0000-0003-2655-0230
dc.authoridBIH, Lahcen/0000-0003-4248-8967
dc.authoridNAKKABI, Asmae/0000-0002-9845-243X
dc.authoridEL YAZIDI, Mohamed/0000-0002-2772-6632
dc.authoridEL MEHDI, HAILY/0000-0001-9260-7659
dc.contributor.authorEs-Sounni, Bouchra
dc.contributor.authorHaily, El Mehdi
dc.contributor.authorNakkabi, Asmae
dc.contributor.authorBakhouch, Mohamed
dc.contributor.authorBejaoui, Linda
dc.contributor.authorKaya, Savas
dc.contributor.authorEl Yazidi, Mohamed
dc.date.accessioned2024-10-26T18:11:30Z
dc.date.available2024-10-26T18:11:30Z
dc.date.issued2022
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractIn this study, a new bi-nuclear nickel complex [Ni2HL2(EtOH)(2)](Cl)(EtOH) of a Schiff base ligand, 2-[3-[2-hydroxybenzylideneamino]propyliminomethyl]phenol, was synthesized and characterized using UV/Vis, IR, HRMS, and TGA/DTA analysis. The molecular structure of the obtained complex was corroborated by the single crystal X-ray diffraction technique. It was found in the complex that two molecules of the ligand coordinate with two nickel atoms through azomethine-N and phenoxy-O, resulting in 6-coordinate distorted octahedral geometry, in which two ethanol molecules occupy the axial positions. The dielectric and electrical properties of the obtained samples were studied by impedance spectroscopy at different frequencies (from 1 Hz to 1 MHz) in the temperature range 298-343 K. It is found that the electrical conductivity of the Ni(II) complex is lower than that of the free ligand H2L, suggesting that the complexation traps the charge carriers contained in the ligand.
dc.identifier.doi10.3390/chemistry4040080
dc.identifier.endpage1207
dc.identifier.issn2624-8549
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85144672433
dc.identifier.scopusqualityQ2
dc.identifier.startpage1193
dc.identifier.urihttps://doi.org/10.3390/chemistry4040080
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30700
dc.identifier.volume4
dc.identifier.wosWOS:000902251000001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofChemistry-Switzerland
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectBi-nuclear complex
dc.subjectoctahedral geometry
dc.subjectspectroscopy
dc.subjectX-ray crystal structure
dc.subjectHirshfeld surface analysis
dc.subjectdielectric
dc.subjectconductivity
dc.titleNew Bi-Nuclear Nickel(II) Complex-Based Salen Schiff Base: Synthesis, Crystal Structure, Spectroscopic, Thermal, and Electrical Investigations
dc.typeArticle

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