Experimental and density functional theoretical modeling of triazole pesticides extraction by Ti2C nanosheets as a sorbent in dispersive solid phase extraction method before HPLC-MS/MS analysis

Basit Öğe Kaydı
dc.authoridGhalkhani, Masoumeh/0000-0001-9246-1805
dc.contributor.authorKhosrowshahi, Elnaz Marzi
dc.contributor.authorMogaddam, Mohammad Reza Afshar
dc.contributor.authorJavadzadeh, Yousef
dc.contributor.authorAltunay, Nail
dc.contributor.authorTuzen, Mustafa
dc.contributor.authorKaya, Savas
dc.contributor.authorGhalkhani, Masoumeh
dc.date.accessioned2024-10-26T18:11:20Z
dc.date.available2024-10-26T18:11:20Z
dc.date.issued2022
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractIn this research, a convenient, fast, and green dispersive solid phase extraction procedure based on Ti2C nanosheets was developed for effectively enrichment of some triazole pesticides prior to high performance liquid chromatography-tandem mass spectrometry. Characterization of the etching sorbent was carried out in details. Adsorption and desorption steps have been optimized in detail to obtain efficient phase separation and reliable analytical results. Under optimized conditions, the presented method exhibited a wide working range (0.52-1000 ng mL(-1)), low detection limits (0.03-0.30 ng mL(-1)) and acceptable extraction recoveries (70-75%). The introduced method precision was checked by calculating intra and inter-day relative standard deviations for three different concentrations of triazole pesticides. The matrix effect was investigated by the recovery study. Following validation studies, the presented method was successfully applied to the extraction and determination of the studied triazole pesticides from fruit juice samples. The adsorption mechanism was supported by theoretical studies. The interactions between the studied pesticides and Ti2C nanosheets were investigated with the help of density functional theoretical calculations. The calculations supported the obtained experimental results.
dc.description.sponsorshipIran National Science Foun-dation (INSF) [98014727]
dc.description.sponsorshipThe authors would like to thanks the Iran National Science Foun-dation (INSF) for the financial support as research No. of 98014727.
dc.identifier.doi10.1016/j.microc.2022.107331
dc.identifier.issn0026-265X
dc.identifier.issn1095-9149
dc.identifier.scopus2-s2.0-85125766698
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.microc.2022.107331
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30625
dc.identifier.volume178
dc.identifier.wosWOS:000919203300001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofMicrochemical Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectMXene
dc.subjectDispersive solid phase extraction
dc.subjectLiquid chromatography-tandem mass spectrometry
dc.subjectPesticides
dc.subjectTheoretical studies
dc.titleExperimental and density functional theoretical modeling of triazole pesticides extraction by Ti2C nanosheets as a sorbent in dispersive solid phase extraction method before HPLC-MS/MS analysis
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu