Headspace ?-solid phase extraction of 1,4-dioxane and 2-methyl-1,3-dioxolane from shampoo samples in a home-mode device and large volume injection of deep eutectic solvent: Theoretical and experimental studies

Basit Öğe Kaydı
dc.contributor.authorMogaddam, Mohammad Reza Afshar
dc.contributor.authorAltunay, Nail
dc.contributor.authorTuzen, Mustafa
dc.contributor.authorKatin, Konstantin P.
dc.contributor.authorNemati, Mahboob
dc.contributor.authorLotfipour, Farzaneh
dc.date.accessioned2024-10-26T18:09:52Z
dc.date.available2024-10-26T18:09:52Z
dc.date.issued2022
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractIn the current study, a headspace micro solid-phase extraction was developed for extraction of 1,4-dioxane and 2-methyl-1,3-dioxolane from shampoo samples. After extraction, the quantities of analytes were determined using the large volume injection method followed by gas chromatography-flame ionization detector. Octadecylsilane, menthol: formic acid deep eutectic solvent, and 1,3-dioxane were used as adsorbent, eluent, and internal standard, respectively. Under optimum conditions, linear ranges for target analytes were from 0.30 to 5000 ng mL-1, and 0.43-5000 ng mL-1 with correlation coefficients 0.9972. The limits of detection were 0.08 and 0.11 ng mL-1 for 1,4-dioxane and 2-methyl-1,3-dioxolane, respectively. The limits of quantification were 0.28 and 0.43 ng mL-1 for 1,4-dioxane and 2-methyl-1,3-dioxolane, respectively. The intra- and inter-day precisions for target analytes at the spiked level of 25 ng mL-1 were < 4.2%. The feasibility of the recommended procedure was successfully tested for the extraction and determination of 1,4-dioxane and 2-methyl-1,3-dioxolane in shampoo samples. The extraction recoveries were ranged from 89 to 90% with relative standard deviations<5.1%. The nature of the interactions between studied chemical species was investigated in the light of conceptual density functional theoretical calculations. As to conclude, it was seen that experimental observations are compatible with the theoretical explanations made according to hard and soft (Lewis) acids and bases Principle.
dc.description.sponsorshipResearch Council of Tabriz University of Medical Sciences [62695]
dc.description.sponsorshipThe authors thank the Research Council of Tabriz University of Medical Sciences for financial support under grant number of 62695.
dc.identifier.doi10.1016/j.microc.2021.107040
dc.identifier.issn0026-265X
dc.identifier.issn1095-9149
dc.identifier.scopus2-s2.0-85120901601
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.microc.2021.107040
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30312
dc.identifier.volume173
dc.identifier.wosWOS:000736661000007
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofMicrochemical Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectHeadspace micro solid phase extraction
dc.subjectGas chromatography
dc.subjectShampoo samples
dc.subject4-Dioxane
dc.subject2-Methyl-1
dc.subject3-dioxolane
dc.titleHeadspace ?-solid phase extraction of 1,4-dioxane and 2-methyl-1,3-dioxolane from shampoo samples in a home-mode device and large volume injection of deep eutectic solvent: Theoretical and experimental studies
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu