Zeolite/Cellulose Acetate (ZCA) in Blend Fiber for Adsorption of Erythromycin Residue From Pharmaceutical Wastewater: Experimental and Theoretical Study

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dc.authoridHanbali, Ghadir/0000-0002-0322-5665
dc.authoridDAGDAG, Omar/0000-0002-9723-1344
dc.contributor.authorJodeh, Shehdeh
dc.contributor.authorErman, Israa
dc.contributor.authorHamed, Othman
dc.contributor.authorMassad, Younes
dc.contributor.authorHanbali, Ghadir
dc.contributor.authorSamhan, Subhi
dc.contributor.authorDagdag, Omar
dc.date.accessioned2024-10-26T18:09:16Z
dc.date.available2024-10-26T18:09:16Z
dc.date.issued2021
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractThe expanding amount of remaining drug substances in wastewater adversely affects both the climate and human well-being. In the current investigation, we developed new cellulose acetic acid derivation/zeolite fiber as an effective technique to eliminate erythromycin (ERY) from wastewater. The number of interchangeable sites in the adsorbent structures and the ratio of ERY to the three adsorbents were identified as the main reasons for the reduction in adsorption as the initial ERY concentrations increased. Additionally, for all adsorbents, the pseudo-second-order modeling showed better fitting for the adsorption than the pseudo-first-order modeling. However, the findings obtained in the pseudo-first-order model were still enough for explaining the sorption kinetics of ERY, showing that the surface displayed all chemisorption and physi-sorption adsorption processes by both adsorbents. The R (2) for the second order was very close to 1 for the three adsorbents in the case of pseudo-second-order. The adsorption capacity reached 17.76 mg/g. The three adsorbents showed negative values of Delta H, and these values were -6,200, -8,500, and -9600 kJ/mol for zeolite, CA, and ZCA, respectively, and this shows that the adsorption is exothermic. The desorption analysis shows no substantial loss of adsorption site after three trials, indicating higher stability and resilience of the three adsorbents, indicating a strong repeatability of their possible use in adsorption without contaminating the environment. In addition, the chemical attitude and possible donor-acceptor interactions of ERY were assessed by the quantum chemical parameters (QCPs) and NBO analysis performed, at the HF/6-311G** calculations.
dc.description.sponsorshipPalestinian Water Authority; Midle East Desalination Research Center (MEDRC); Shahid Chamran University of Ahvaz; University of Tehran
dc.description.sponsorshipThe authors would like to thank both the Palestinian Water Authority and the Midle East Desalination Research Center (MEDRC) for their help and financial support through the I2 Innovation program. The authors would like to express their gratitude to the Shahid Chamran University of Ahvaz and the University of Tehran for their financial support of this research. The authors would also like to thank Turkey's Scientific and Technological Research Council (TUBITAK). The High Performance and Grid Computing Center (TR-Grid e-Infrastructure) has been used for all quantum chemical calculations.
dc.identifier.doi10.3389/fchem.2021.709600
dc.identifier.issn2296-2646
dc.identifier.pmid34336793
dc.identifier.scopus2-s2.0-85111413700
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.3389/fchem.2021.709600
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30035
dc.identifier.volume9
dc.identifier.wosWOS:000679104200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherFrontiers Media Sa
dc.relation.ispartofFrontiers in Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectpharmaceutical industry
dc.subjectadsorption capacity
dc.subjectwastewater
dc.subjectcellulose
dc.subjectzeolite
dc.titleZeolite/Cellulose Acetate (ZCA) in Blend Fiber for Adsorption of Erythromycin Residue From Pharmaceutical Wastewater: Experimental and Theoretical Study
dc.typeArticle

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