Synthesis of non-peripherally tetra-substituted copper(ii) phthalocyanines: characterization, optical and surface properties, fabrication and photo-electrical properties of a photosensitive diode

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dc.authoridTUZUN, BURAK/0000-0002-0420-2043
dc.authoridGunsel, Armagan/0000-0003-1965-1017
dc.authoridPiskin, Hasan/0000-0001-9927-4930
dc.authoridGunduz, Bayram/0000-0002-1447-7534
dc.authoridYarasir, Meryem Nilufer/0000-0002-7327-7137
dc.authoridBILGICLI, Ahmet Turgut/0000-0002-4144-7357
dc.contributor.authorGunsel, Armagan
dc.contributor.authorBilgicli, Ahmet T.
dc.contributor.authorPiskin, Hasan
dc.contributor.authorTuzun, Burak
dc.contributor.authorYarasir, M. Nilufer
dc.contributor.authorGunduz, Bayram
dc.date.accessioned2024-10-26T18:09:27Z
dc.date.available2024-10-26T18:09:27Z
dc.date.issued2019
dc.departmentSivas Cumhuriyet Üniversitesi
dc.description.abstractThis study describes the synthesis and characterization of a non-peripherally tetra-substituted copper(ii) phthalocyanine bearing 4-(trifluoromethoxy)phenol groups. Some spectroscopic techniques such as FT-IR, H-1-NMR, C-13-NMR, MALDI-TOF, SEM and UV-vis were used to characterize the compounds. The novel molecule of 3-(4-(trifluoromethoxy) phenoxy) phthalonitrile (1) was confirmed and its molecular structure and supra-molecular dynamics were revealed by the analysis of single crystal X-ray diffraction measurements. Ligand (1) and its copper(ii) phthalocyanine (2) were theoretically examined via HF and B3LYP, M06-2X methods by using the 3-21G, 6-31G and sdd basis sets. The calculated values of IR, NMR and UV-Vis spectra for ligand (1) and its copper(ii) phthalocyanine (2) were compared with the experimentally obtained values. The absorbance and reflectance spectra, optical band gaps, refractive indices, and the optical and electrical conductivities of compound (2) for different concentrations were investigated in detail. We fabricated a photosensitive diode and investigated its photo-electrical properties under dark and light conditions.
dc.identifier.doi10.1039/c9dt02868d
dc.identifier.endpage14852
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue39
dc.identifier.pmid31553336
dc.identifier.scopus2-s2.0-85072993116
dc.identifier.scopusqualityQ1
dc.identifier.startpage14839
dc.identifier.urihttps://doi.org/10.1039/c9dt02868d
dc.identifier.urihttps://hdl.handle.net/20.500.12418/30117
dc.identifier.volume48
dc.identifier.wosWOS:000489155800030
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.ispartofDalton Transactions
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleSynthesis of non-peripherally tetra-substituted copper(ii) phthalocyanines: characterization, optical and surface properties, fabrication and photo-electrical properties of a photosensitive diode
dc.typeArticle

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