Crystal structure of 2-[(3S, 4S)-4-(anthracen-9-yl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]-2-aza-2H-phenalene-1,3-dione unknown solvate
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The central beta-lactam ring of the title compound, C36H24N2O4, is almost planar (r.m.s. deviation = 0.003 angstrom) and makes dihedral angles of 17.17 (19), 89.76 (17) and 78.44 (17)degrees with the benzene ring, the anthracene ring (r.m.s. deviation = 0.003 angstrom) and the 1H-benzo[de] isoquinoline-1,3(2H)-dione moiety, which is nearly planar [maximum deviation = 0.098 (2) angstrom], respectively. The molecular structure is stabilized by an intramolecular C-H center dot center dot center dot N hydrogen bond. In the crystal, molecules are linked via C-H center dot center dot center dot pi and pi-pi stacking interactions [centroid-centroid distances = 3.5270 (19) and 3.779 (2) angstrom], forming a three-dimensional structure. A region of disordered electron density, probably disordered solvent molecules, was treated with the SQUEEZE procedure in PLATON [Spek (2015). Acta Cryst. C71, 9-18], which indicated a solvent cavity of 322 angstrom(3) containing approximately 91 electrons. Their formula mass and unit-cell characteristics were not taken into account during the refinement.
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Hilmi Ataseven; İlhami Yüksel; Mehmet İbiş; Bülent Ödemiş; Mehmet Arhan; Bahattin Çiçek; Dilek Oğuz; Mesut Zeki Yalın Kılıç; Oğuz Üsküdar; Engin Uçar; Emin Altıparmak (2011)Amaç. HDV ile enfektia kronik hepatit hastalarımızın cilt altı interferon tedavisi sonrası takip sonuçlarını sunmak. Yöntem. Toplam 24 hastanın (21 Erkek, 3 Kadın) HBsAg (+), AntiHBc IgM (-), hepatit D virüsüne karşı antikor ...
The place of computed tomography as a guidance modality in percutaneous nephrostomy: Analysis of a 10-year single-center experience Egilmez, H.; Oztoprak, I.; Atalar, M.; Cetin, A.; Gumus, C.; Gultekin, Y.; Bulut, S.; Arslan, M.; Solak, O. (TAYLOR & FRANCIS LTD, 2007)Background: Percutaneous nephrostomy ( PCN) has been established as an effective technique for urinary decompression or diversion. This procedure may be performed with the guidance of fluoroscopy, ultrasonography, a ...
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