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Öğe Advanced evaluation of novel quinoline derivatives for corrosion inhibition of mild steel in acidic environments: A comprehensive electrochemical, computational, and surface study(Elsevier, 2024) Belkheiri, Azzeddine; Dahmani, Khadija; Mzioud, Khaoula; Rbaa, Mohamed; Galai, Mouhsine; Hmada, Abdelfettah; Erdogan, SabanCorrosion poses a significant threat to the integrity and longevity of iron and its alloys, which are crucial materials for modern industry and infrastructure. This study investigates the effectiveness of two recently synthesized inhibitors based on quinoline structures: MPQ (2-methyl-5-(propoxymethyl) quinolin-8-ol) and AAQ ((((2aminoethyl)amino)methyl)-2-methylquinolin-8-ol) in protecting steel against environmental degradation, particularly in acidic and chloride-rich conditions such as hydrochloric acid. The inhibitors exhibited significant corrosion inhibition efficiencies of 92.37 % for MPQ and 84.13 % for AAQ, as demonstrated through electrochemical analysis. Surface characterization techniques, including SEM-EDX(Scanning Electron Microscopy with Energy Dispersive X-ray analysis), AFM (Atomic Force Microscopy), and contact angle measurements, revealed the formation of a protective barrier film that reduces the corrosion rate. Additionally, theoretical calculations using the Gaussian package provided insights into the adsorption behaviors and protective mechanisms of the inhibitors on mild steel surfaces. The findings contribute to the ongoing search for viable corrosion inhibitors, offering prospects for application in industries and critical infrastructures to enhance corrosion protection and durability.Öğe Development process for eco-friendly corrosion inhibitors(Elsevier, 2022) Rbaa, Mohamed; Galai, Mouhsine; Dagdag, Omar; Guo, Lei; Tüzün, Burak; Berdimurodov, Elyor; Zarrouk, AbdelkaderCurrently, the eco-friendly corrosion inhibitors are widely used to protect the metallic materials from the corrosion destruction. The eco-friendly corrosion inhibitors are biodegradable, low toxic, low volatile, low cost, good water soluble, good adsorbent, and do not contain heavy metals or other toxic compounds. The plant extracts and natural substances are suggested as an eco-friendly corrosion inhibitors in the various corrosion medium. The corrosion of steel, copper, magnesium, aluminum and other metal based metallic materials in the aggressive acidic, alkaline, saline and other corrosion medium are efficiently protect with the presence of eco-friendly corrosion inhibitors. The cost in the synthesizing natural inhibitors is very low and syntheses processes are environmental friendly. This make eco-friendly corrosion inhibitors become more efficient as an economically and environmentally. In this chapter, the development process for eco-friendly corrosion inhibitors, their advantages and their inconveniences are discussed and reviewed. © 2022 Elsevier Inc. All rights reserved.Öğe Development process for ecofriendly corrosion inhibitors(26.07.2022) Rbaa, Mohamed; Galai, Mouhsine; Dagdag, Omar; Guo, Lei; Tüzün,Burak; Berdimurodov, Elyor; Zarrouk, Abdelkader; Lakhrissi, BrahimThe metallic materials are main used materials, because, their physical properties, such as electrical conduction, thermal conduction, and mechanical performances. The steel based metallic materials are most common in the gas and oil industry [1–3]. However, a high percentage of the steel materials are damaged by corrosion in acidic environments [4]. Therefore, to protect steel materials is ongoing problem. Currently, many researches are interested to going research in the corrosion protection.Öğe Ionic liquids as green and sustainable corrosion inhibitors I(Elsevier, 2022) Berdimurodov, Elyor; Kholikov, Abduvali; Akbarov, Khamdam; Guo, Lei; Umirov, Nurbek; Verma, Dakeshwar Kumar; Rbaa, MohamedThe corrosion of metal materials is an ongoing problem in the chemical industry. The use of sustainable and green technologies in corrosion protection is a very important task, because, the rise in environmental and ecological awareness. Currently, ionic liquids (ILs) based corrosion inhibitors are widely performed to protect the metal materials from the aggressive corrosion environment in the chemical industry. This is due to the ionic liquids are environmental-friendly, more sustainable, and have excellent corrosion-resistance organic molecules at low concentrations. In addition, the ILs are good soluble, non-toxic behaviour, non-inflammability, low volatility, good adsorbent, high thermal, and chemical stable in the aggressive medium. Besides, ILs have large planer anionic and cationic groups, which support an intermolecular synergism behavior; as a result, the adsorption of ILs is increased. These properties make ILs be a more efficient inhibitor. The ILs effectively protect the metal materials included steel, copper, magnesium, zinc and aluminum in the acid cleaning, descaling, pickling, gas or oil processes and desalination applications. In this chapter, the types, inhibition mechanism, inhibition properties of ILs, theoretical and experimental insights in the ILs inhibition mechanism were reviewed. © 2022 Elsevier Inc. All rights reserved.Öğe Multifunctional Magnetic Nanoparticles in Hyperthermia Therapy(CRC Press, 2024) Rbaa, Mohamed; Hichar, Abdelhadi; Oubaaqa, Mohamed; Seghiri, Rajaa; Berdimurodov, Elyor; Tüzün, Burak; Zarrouk, AbdelkaderAn overview of the writing on the application of multifunctional magnetic nanoparticles (MF-MNP) in hyperthermia treatment is given in this chapter. With their special attractive characteristics, these MF-MNP can be utilized to target and wipeout warm tissues. These magnetic nanoparticles with numerous capacities can also cause hyperthermia. They have an assortment of capacities that permit them to be utilized in a wide range of settings, such as demonstrative imaging and applications like destroying cancer cells. MF-MNP has incredible possibilities for progressing the treatment of infection. © 2025 selection and editorial matter, Edited by Elyor Berdimurodov, Chaudhery Mustansar Hussain, and Burak Tüzün; individual chapters, the contributors.Öğe Multifunctional Magnetic Nanoparticles in the Separation and Detection of Biological Molecules: Proteins, Enzymes, and Nucleic Acid(CRC Press, 2024) Kul, I˙layda Bersu; Tüzün, Gamze; Tüzün, Burak; Berdimurodov, Elyor; Rbaa, MohamedThis chapter showcases the various advantages of magnetic nanoparticles. It emphasizes the importance of nanoparticles in the identification and isolation of biological molecules such as proteins, nucleic acids, and enzymes. First, the basic properties and synthesis methods of magnetic nanoparticles are explained in detail, especially the interaction with proteins, nucleic acids, and enzymes. The importance of magnetic nanoparticles in the separation and purification of various biological molecules is emphasized. Finally, this chapter explains the functions of magnetic nanoparticles in the field of biomedicine and medicine, as well as in the diagnosis of various diseases. © 2025 selection and editorial matter, Edited by Elyor Berdimurodov, Chaudhery Mustansar Hussain, and Burak Tüzün; individual chapters, the contributors.Öğe New and Green Corrosion Inhibitor Based on New Imidazole Derivate for Carbon Steel in 1 M HCl Medium: Experimental and Theoretical Analyses(Trans Tech Publications Ltd, 2022) Berdimurodov, Elyor; Kholikov, Abduvali; Akbarov, Khamdam; Guo, Lei; Kaya, Savas; Verma, Dakeshwar Kumar; Rbaa, MohamedIn this research work, a new and green corrosion inhibitor based on new imidazole derivate (IMD) was introduced for carbon steel in 1 M HCl medium. Its inhibition properties were fully characterised by the gravimetric, electrochemical, surface and quantum chemical analyses. The experimental results confirmed that the inhibition efficiency of IMD was over 99% at 150 mg/L, forming a protective hydrophobic film on the metal surface, which maximally blocked the cathodic and anodic corrosive processes by adsorption. The electrochemical results suggested that the IMD is a mixed-type inhibitor. The adsorption behaviour of IMD was obeyed by Langmuir isotherms. The gravimetric results show that the inhibition efficiency depends on the change of concentration and temperature. The experimental tests were supported by the DFT (density functional theory) measurements, and a good relationship was found among these tests. The observed results of the surface analysis indicated that the metal surface was seriously improved with the presence of IMD.Öğe Novel cucurbit[6]uril-based [3]rotaxane supramolecular ionic liquid as a green and excellent corrosion inhibitor for the chemical industry(Elsevier, 2022) Berdimurodov, Elyor; Kholikov, Abduvali; Akbarov, Khamdam; Guo, Lei; Katin, Konstantin P.; Verma, Dakeshwar Kumar; Rbaa, MohamedThe corrosion of steel materials in alkaline-saline media is the largest problem in industry. Economical and environmentally friendly corrosion inhibitors are crucial for corrosion protection. The present work is the first to introduce a novel cucurbit[6]uril-based [3]rotaxane supramolecular ionic liquid (CB6-based [3]rotaxane) as a green and efficient corrosion inhibitor for the chemical industry. The correlation between the supramolecular ionic liquid system and inhibition behavior was studied first. The inhibition characteristics of CB6-based [3] rotaxane in 1 M OH- + 1 M Cl- solution were first fully investigated by thermodynamic, gravimetric, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), electrochemical noise (EN), cyclic voltammetry (CV), density functional theory (DFT), molecular dynamics (MD) simulation, scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX) methods. The experimental results confirmed that CB6-based [3]rotaxane exhibited excellent corrosion resistance, and its inhibition efficiency was 97.97% at 100 mg/L and 0.032 mM. The electrochemical results suggested that (i) CB6-based [3]rotaxane was a mixed-type corrosion inhibitor with anodic dominance; (ii) the supramolecular part of selected ionic liquid is responsible for notably blocks the charge transfer process on the metal surface. The theoretical findings correlated well with the experimental results and revealed that the protonated form of this supramolecular structure exhibited better performance than its neutral form. MD simulations results suggested that the bond length of the Fe(surface)inhibitor (3.127 angstrom) is less than 3.5 angstrom, which indicates that chemisorption is dominant in the investigated adsorption system. Molecular electrostatic potential analysis confirmed that the studied ionic liquidsupramolecular system contained most favorable nucleophilic centers, which are responsible for excellent inhibition performance.Öğe Novel glycoluril pharmaceutically active compound as a green corrosion inhibitor for the oil and gas industry(Elsevier Science Sa, 2022) Berdimurodov, Elyor; Kholikov, Abduvali; Akbarov, Khamdam; Guo, Lei; Kaya, Savas; Verma, Dakeshwar Kumar; Rbaa, MohamedBackground: The corrosion of St3 steel in 1 M NaCl saturated with CO2 and H2S is a large problem in the chemical industry; therefore, creating green and more efficient inhibitors is an urgent task. However, there have been extremely limited research results related to this problem. In this research, a novel glycoluril pharmaceutically active compound (GCU) was first introduced as a green corrosion inhibitor for St3 steel in 1 M NaCl saturated with CO2 and H2S. Methods: The inhibition properties of the novel glycoluril pharmaceutically active compound were fully characterized by thermodynamic, gravimetric, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), electrochemical frequency modulation (EFM), linear polarization resistance (LPR), density functional theory (DFT), molecular dynamics (MD) simulation, scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX) methods. Significant findings: The obtained results indicated that this inhibitor is an excellent inhibitory molecule, and its maximum protection degree was 95.62% at 100 mg/L/0.08 mM. The adsorption behaviour of this inhibitor was characterized from a Langmuir isotherm. Electrochemical studies demonstrated that this molecule is a mixed-type corrosion inhibitor. The theoretical calculations indicated a good correlation with the experimental results and confirmed that the adsorption-inhibition character depends on the molecular structure of the inhibitor and that the protonated form of the inhibitor is more inhibited than its neutral form.Öğe Preparation of Multifunctional Nanoparticles for Applications in Biomedicine(CRC Press, 2024) Rbaa, Mohamed; Seghiri, Rajaa; Oubaaqa, Mohamed; Tüzün, Burak; Berdimurodov, Elyor; Zarrouk, AbdelkaderIn this chapter, we look at the definitions and characteristics of multifunctional magnetic nanoparticles (MNPs), as well as their volume and size. We also explore the uses of multifunctional magnetic nanoparticles (MNPs) in biomedicine, specifically in nuclear magnetic resonance imaging (MRI), and the early detection of diseases. Additionally, we go over a number of chemical and biological synthesis techniques for synthesizing multifunctional magnetic nanoparticles, emphasizing the benefits of these approaches over others. © 2025 selection and editorial matter, Edited by Elyor Berdimurodov, Chaudhery Mustansar Hussain, and Burak Tüzün; individual chapters, the contributors.Öğe Synthesis methods and description for new derivatives associated with 8-hydroxyquinoline and their use as acidic corrosion inhibitors for steel and other alloys: a review(Walter De Gruyter Gmbh, 2024) Rbaa, Mohamed; Berdimurodov, Elyor; Tuzun, Burak; Berdimuradov, Khasan; Zarrouk, AbdelkaderThe field of corrosion has recently been considered a productive field for scientific research. With the increasing use of metals in several industrial fields, such as metal construction, the construction of arches and the automobile industry, the problem of corrosion is an important issue. To solve the corrosion problem of metal materials, several methods have been discovered to combat this phenomenon, such as process control, cathodic protection, organic and inorganic coatings. Nonetheless, the presentation of corrosion inhibitors, particularly organic inhibitors, stays the least expensive and simplest technique for the insurance of metals against consumption in acidic media. In this work, it was summed up the strategies for amalgamation and portrayal of newly innovative heterocyclic complexes from 8-hydroxyquinoline, their inhibition performances for M-steel, C40E steel and C35E steel in acidic conditions, for example, hydrochloric acid, sulfuric acid, etc.Öğe Synthesis, bioinformatics and biological evaluation of novel pyridine based on 8-hydroxyquinoline derivatives as antibacterial agents: DFT, molecular docking and ADME/T studies(Elsevier, 2021) Rbaa, Mohamed; Oubihi, Asmaa; Hajji, Halima; Tuzun, Burak; Hichar, Abdelhadi; Anouar, El Hassane; Berdimurodov, ElyorY The present study aims to first explore the relationship between the chemical structure of the organic compounds (pyridine based on 8-hydroxyquinoline) and the antibacterial activities, as well as the impact of substituent effects on their antibacterial properties. These compounds were synthesized by efficient methods, and their structures confirmed by the spectral methods (IR, H-1 NMR, C-13 NMR and elemental analysis). The antibacterial activities of synthesized the compounds were checked with five Gram-positive and Gram-negative strains such as Enterobacter cloacae (ATCC29893),Escherichia coli (ATCC35218), Klebsiella pneumoniae (ATCC13883), Staphylococcus aureus (ATCC29213) and Acinetobacter baumannii (ATCC19606). The results of the antibacterial activities of four synthesized compounds were compared with three standard antibiotics [Penicillin G, Erythromycin and Norfloxacin (quinoline type)]. The minimum inhibitory concentrations (MICs) of active compounds were calculated and discussed. The chemical and biological activities of hydroxyquinoline derivatives were compared with theoretical methods. The chemical activities of hydroxyquinoline derivatives were contrasted with the important quantum chemical parameters using the HF/6-31++ g (d, p) basis sets. Besides, biological activities of hydroxyquinoline derivatives against cancer proteins that are respectively protein of the BRCT repeat region of breast cancer that is ID: 1JNX, crystal structure of liver cancer protein that is ID: 3WZE, and crystal structure of lung cancer protein that is ID: 5ZMA, were compared. ADME/T (Adsorption, Distribution, Metabolism, Excretion, and Toxicity) analysis was studied for molecules with high biological activity to become efficient drugs in the future. (C) 2021 Elsevier B.V. All rights reserved.Öğe Synthesis, characterization and bioactivity of novel 8-hydroxyquinoline derivatives: Experimental, molecular docking, DFT and POM analyses(Elsevier, 2022) Rbaa, Mohamed; Haida, Sara; Tuzun, Burak; Hichar, Abdelhadi; El Hassane, Anouar; Kribii, Abderahim; Lakhrissi, YounesIn this present research work, new 8-hydroxyquinoline derivatives were synthesized and their molecular structures were confirmed by the H-1 NMR, C-13 NMR, IR and elemental analysis. The antioxidant activity of the synthesized compounds is evaluated through their capacity to scavenge 2,2-di-phenyl-1picrylhydrazyl (DPPH) free radicals. In addition, their antibacterial activity was examined against bacterial strains of S. aureus, K. pneumonia, and E. coli. The obtained results showed that the antibacterial activity of studied compounds for Gram-positive and Gram-negative is higher than Penicillin G. The theoretical properties of selected compounds was computed by the DFT method. POM analysis (Petra/Osiris/Molinspiration) of studied molecules has been done. Their biological activities were compared against breast, liver and lung cancer proteins. The obtained results showed the synthesized derivatives were effective antibacterial and antioxidant agents against various biological material. (c) 2022 Elsevier B.V. All rights reserved.Öğe Synthesis, structural confirmation, antibacterial properties and bio-informatics computational analyses of new pyrrole based on 8-hydroxyquinoline(Elsevier, 2022) Lakhrissi, Younes; Rbaa, Mohamed; Tuzun, Burak; Hichar, Abdelhadi; Anouar, El Hassane; Ounine, Khadija; Almalki, FaisalThis study aims to synthesize new pyrrolic compounds derivatives of 8-hydroxyquinoline, explore the structure-activity relationship and the effect of the substituents carried by the pyrrole ring on their antibacterial properties. These compounds were characterized by IR, H-1, C-13 NMR and elemental analysis. The NMR predicted chemical shifts were determined by the GIAO approach and the solvent effect was taken into account using the polarizable continuum model (PCM). The evaluation of the antibacterial activity was carried out in vitro against three bacterial strains namely; E. coli (ATCC35218), S. aureus (ATCC29213) and P. aeruginosa (ATCC27853) using the disk method. The results of antibacterial activity were compared with those of a standard antibiotic (Norfloxacin). The Minimum Inhibitory Concentrations (MICs) were calculated and discussed. The results of the experimental tests were supported by bioinformatics Docking, DFT and POM studies. (C) 2022 Elsevier B.V. All rights reserved.Öğe Synthesis, Structural confirmation, Antibacterial Properties and Bio-Informatics Computational Analyses of New Pyrrole Based on 8-Hydroxyquinoline (vol 1259, 132683, 2022)(Elsevier, 2023) Lakhrissi, Younes; Rbaa, Mohamed; Tuzun, Burak; Hichar, Abdelhadi; Anouar, El Hassane; Ounine, Khadija; Almalki, Faisal[Abstract Not Available]
