Intake of divalent copper and nickel onto natural zeolite from aqueous solutions: a study in mono- and dicomponent systems

dc.contributor.authorTekin, Burak
dc.contributor.authorAçıkel, Ünsal
dc.date.accessioned2023-06-19T09:40:26Z
dc.date.available2023-06-19T09:40:26Z
dc.date.issued2022tr
dc.departmentMühendislik Fakültesitr
dc.description.abstractIn this study, the noncompetitive and competitive adsorption process of copper (II) and nickel (II) ions on the natural zeolite were examined in simulated wastewater in a batch system with respect to concentration, pH and temperature. Optimum pH values were found as 5,0 for adsorption of copper and nickel ions on the zeolite. The effect of initial concentration and ambient temperature on the yield of adsorption was examined at this pH value. The equilibrium adsorption data of Cu (II) and Ni (II) onto the zeolite were analyzed by the Langmuir’s and Freundlich’s isotherms, and the experimental metal uptake data fitted well with both isotherm models. In case of the presence of simultaneous multimetal ions in the aqueous phase, the adsorption capacity of the adsorbent is slightly low probably due to the competitive uptake of each metal ion by the adsorbent. For the metal sorption system, the negative Gibbs free energy values show the applicability and spontaneous nature of the metal uptake treatment by the zeolite. The activation energy and enthalpy change of divalent cation adsorption demonstrate that the intake of Cu (II) and Ni (II) onto the zeolite involves not only a chemical adsorption process but also a physical adsorption process.tr
dc.identifier.citationBurak TEKİN1 *, Ünsal AÇIKEL2  1 Department of Chemical Engineering, 19 Mayıs University, Samsun, Turkey 2 Department of Chemical Engineering, Cumhuriyet University, Sivas, Turkeytr
dc.identifier.doi10.55730/1300-0527.3413en_US
dc.identifier.pmid37538779en_US
dc.identifier.scopus2-s2.0-85137383961en_US
dc.identifier.scopusqualityN/A
dc.identifier.trdizinid1141978en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12418/13715
dc.identifier.wosWOS:000895319000008en_US
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.relation.publicationcategoryUlusal Hakemli Dergide Makale - Kurum Öğretim Elemanıtr
dc.rightsinfo:eu-repo/semantics/openAccesstr
dc.subjectAdsorption, Natural zeolite, mono- and dicomponent adsorption, Cu (II) and Ni (II) contaminantstr
dc.titleIntake of divalent copper and nickel onto natural zeolite from aqueous solutions: a study in mono- and dicomponent systemsen_US
dc.typeArticleen_US

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